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Unusual molecular complexes of antimony fluoride dimers with acetonitrile and pyridine : structures and bonding. / Davydova, Elena I.; Virovets, Alexander; Peresypkina, Eugenia; Pomogaeva, Anna V.; Lisovenko, Anna S.; Timoshkin, Alexey Y.

в: Dalton Transactions, Том 50, № 38, 05.10.2021, стр. 13357-13367.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

Harvard

Davydova, EI, Virovets, A, Peresypkina, E, Pomogaeva, AV, Lisovenko, AS & Timoshkin, AY 2021, 'Unusual molecular complexes of antimony fluoride dimers with acetonitrile and pyridine: structures and bonding', Dalton Transactions, Том. 50, № 38, стр. 13357-13367. https://doi.org/10.1039/d1dt02412d

APA

Davydova, E. I., Virovets, A., Peresypkina, E., Pomogaeva, A. V., Lisovenko, A. S., & Timoshkin, A. Y. (2021). Unusual molecular complexes of antimony fluoride dimers with acetonitrile and pyridine: structures and bonding. Dalton Transactions, 50(38), 13357-13367. https://doi.org/10.1039/d1dt02412d

Vancouver

Davydova EI, Virovets A, Peresypkina E, Pomogaeva AV, Lisovenko AS, Timoshkin AY. Unusual molecular complexes of antimony fluoride dimers with acetonitrile and pyridine: structures and bonding. Dalton Transactions. 2021 Окт. 5;50(38):13357-13367. https://doi.org/10.1039/d1dt02412d

Author

Davydova, Elena I. ; Virovets, Alexander ; Peresypkina, Eugenia ; Pomogaeva, Anna V. ; Lisovenko, Anna S. ; Timoshkin, Alexey Y. / Unusual molecular complexes of antimony fluoride dimers with acetonitrile and pyridine : structures and bonding. в: Dalton Transactions. 2021 ; Том 50, № 38. стр. 13357-13367.

BibTeX

@article{fe082ab3c31445ed9f7356f6873b2fe3,
title = "Unusual molecular complexes of antimony fluoride dimers with acetonitrile and pyridine: structures and bonding",
abstract = "The structures of two new molecular complexes of antimony pentafluoride with pyridine (Py) and acetonitrile (AN), SbF5·Py and Sb2F10·AN, and a molecular complex of antimony trifluoride Sb2F6·Py and its ionic derivative [HPy]+[Sb2F7]−in the solid state have been determined by single crystal X-ray structural analysis. The complexes Sb2F10·AN and Sb2F6·Py are the first structurally characterized compounds of dimeric antimony fluorides. To reveal the nature of bonding in the complexes and their stability, DFT computations of the electronic structure and thermodynamic characteristics were performed, in particular the analysis of the electrostatic potentials, the orbital interactions and the topology. The results indicate that the intermolecular Sb⋯F interactions can be described as a network of pnictogen bonds.",
keywords = "CRYSTAL-STRUCTURE, PNICOGEN BONDS, SPECTRA, F-19, PENTAFLUORIDE, REACTIVITY, DENSITY",
author = "Davydova, {Elena I.} and Alexander Virovets and Eugenia Peresypkina and Pomogaeva, {Anna V.} and Lisovenko, {Anna S.} and Timoshkin, {Alexey Y.}",
note = "Publisher Copyright: {\textcopyright} The Royal Society of Chemistry 2021.",
year = "2021",
month = oct,
day = "5",
doi = "10.1039/d1dt02412d",
language = "English",
volume = "50",
pages = "13357--13367",
journal = "Dalton Transactions",
issn = "1477-9226",
publisher = "Royal Society of Chemistry",
number = "38",

}

RIS

TY - JOUR

T1 - Unusual molecular complexes of antimony fluoride dimers with acetonitrile and pyridine

T2 - structures and bonding

AU - Davydova, Elena I.

AU - Virovets, Alexander

AU - Peresypkina, Eugenia

AU - Pomogaeva, Anna V.

AU - Lisovenko, Anna S.

AU - Timoshkin, Alexey Y.

N1 - Publisher Copyright: © The Royal Society of Chemistry 2021.

PY - 2021/10/5

Y1 - 2021/10/5

N2 - The structures of two new molecular complexes of antimony pentafluoride with pyridine (Py) and acetonitrile (AN), SbF5·Py and Sb2F10·AN, and a molecular complex of antimony trifluoride Sb2F6·Py and its ionic derivative [HPy]+[Sb2F7]−in the solid state have been determined by single crystal X-ray structural analysis. The complexes Sb2F10·AN and Sb2F6·Py are the first structurally characterized compounds of dimeric antimony fluorides. To reveal the nature of bonding in the complexes and their stability, DFT computations of the electronic structure and thermodynamic characteristics were performed, in particular the analysis of the electrostatic potentials, the orbital interactions and the topology. The results indicate that the intermolecular Sb⋯F interactions can be described as a network of pnictogen bonds.

AB - The structures of two new molecular complexes of antimony pentafluoride with pyridine (Py) and acetonitrile (AN), SbF5·Py and Sb2F10·AN, and a molecular complex of antimony trifluoride Sb2F6·Py and its ionic derivative [HPy]+[Sb2F7]−in the solid state have been determined by single crystal X-ray structural analysis. The complexes Sb2F10·AN and Sb2F6·Py are the first structurally characterized compounds of dimeric antimony fluorides. To reveal the nature of bonding in the complexes and their stability, DFT computations of the electronic structure and thermodynamic characteristics were performed, in particular the analysis of the electrostatic potentials, the orbital interactions and the topology. The results indicate that the intermolecular Sb⋯F interactions can be described as a network of pnictogen bonds.

KW - CRYSTAL-STRUCTURE

KW - PNICOGEN BONDS

KW - SPECTRA

KW - F-19

KW - PENTAFLUORIDE

KW - REACTIVITY

KW - DENSITY

UR - http://www.scopus.com/inward/record.url?scp=85116656944&partnerID=8YFLogxK

UR - https://www.mendeley.com/catalogue/02deece8-5c0f-3db6-85d3-171753e304d2/

U2 - 10.1039/d1dt02412d

DO - 10.1039/d1dt02412d

M3 - Article

AN - SCOPUS:85116656944

VL - 50

SP - 13357

EP - 13367

JO - Dalton Transactions

JF - Dalton Transactions

SN - 1477-9226

IS - 38

ER -

ID: 87558440