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Unique rheological behavior of detonation nanodiamond hydrosols : The nature of sol-gel transition. / Kuznetsov, Nikita M.; Belousov, Sergey I.; Bakirov, Artem V.; Chvalun, Sergei N.; Kamyshinsky, Roman A.; Mikhutkin, Alexey A.; Vasiliev, Alexander L.; Tolstoy, Peter M.; Mazur, Anton S.; Eidelman, Eugeny D.; Yudina, Elena B.; Vul, Alexander Ya.

в: Carbon, Том 161, 05.2020, стр. 486-494.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

Harvard

Kuznetsov, NM, Belousov, SI, Bakirov, AV, Chvalun, SN, Kamyshinsky, RA, Mikhutkin, AA, Vasiliev, AL, Tolstoy, PM, Mazur, AS, Eidelman, ED, Yudina, EB & Vul, AY 2020, 'Unique rheological behavior of detonation nanodiamond hydrosols: The nature of sol-gel transition', Carbon, Том. 161, стр. 486-494. https://doi.org/10.1016/j.carbon.2020.01.054

APA

Kuznetsov, N. M., Belousov, S. I., Bakirov, A. V., Chvalun, S. N., Kamyshinsky, R. A., Mikhutkin, A. A., Vasiliev, A. L., Tolstoy, P. M., Mazur, A. S., Eidelman, E. D., Yudina, E. B., & Vul, A. Y. (2020). Unique rheological behavior of detonation nanodiamond hydrosols: The nature of sol-gel transition. Carbon, 161, 486-494. https://doi.org/10.1016/j.carbon.2020.01.054

Vancouver

Kuznetsov NM, Belousov SI, Bakirov AV, Chvalun SN, Kamyshinsky RA, Mikhutkin AA и пр. Unique rheological behavior of detonation nanodiamond hydrosols: The nature of sol-gel transition. Carbon. 2020 Май;161:486-494. https://doi.org/10.1016/j.carbon.2020.01.054

Author

Kuznetsov, Nikita M. ; Belousov, Sergey I. ; Bakirov, Artem V. ; Chvalun, Sergei N. ; Kamyshinsky, Roman A. ; Mikhutkin, Alexey A. ; Vasiliev, Alexander L. ; Tolstoy, Peter M. ; Mazur, Anton S. ; Eidelman, Eugeny D. ; Yudina, Elena B. ; Vul, Alexander Ya. / Unique rheological behavior of detonation nanodiamond hydrosols : The nature of sol-gel transition. в: Carbon. 2020 ; Том 161. стр. 486-494.

BibTeX

@article{c84aa2160a1142d8a93c0eb0090521f6,
title = "Unique rheological behavior of detonation nanodiamond hydrosols: The nature of sol-gel transition",
abstract = "The paper describes the data on unusual rheological properties of detonation nanodiamonds (DND) hydrosols and presents the fractal model explaining such behavior. The hydrosols of DND with particles size of 4–5 nm and concentration range of 1.1–7.3 wt% with negative (ζ < 0) and positive (ζ > 0) electrokinetic potentials have been studied by rotational viscometry, small-angle X-ray scattering, nuclear magnetic resonance and Cryo Electron Tomography. Remarkable hysteresis of viscosity and thixotropic effect demonstrate the sol-gel transition at very low concentrations of the DND: 4–5 wt% for ζ > 0 and 5–6 wt% for ζ < 0. The transition is accompanied by increase of loss (viscosity) modulus by two orders of magnitude and the storage (elasticity) modulus started to be detected also. The experimental results have been explained in the frame of percolation theory based on the network formation due to faceted DND particles interactions.",
keywords = "Detonation nanodiamond, Hysteresis of viscosity, Percolation threshold, Rheological properties, Sol-gel transition, Thixotropy, NANO, SMALL-ANGLE SCATTERING",
author = "Kuznetsov, {Nikita M.} and Belousov, {Sergey I.} and Bakirov, {Artem V.} and Chvalun, {Sergei N.} and Kamyshinsky, {Roman A.} and Mikhutkin, {Alexey A.} and Vasiliev, {Alexander L.} and Tolstoy, {Peter M.} and Mazur, {Anton S.} and Eidelman, {Eugeny D.} and Yudina, {Elena B.} and Vul, {Alexander Ya}",
year = "2020",
month = may,
doi = "10.1016/j.carbon.2020.01.054",
language = "English",
volume = "161",
pages = "486--494",
journal = "Carbon",
issn = "0008-6223",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Unique rheological behavior of detonation nanodiamond hydrosols

T2 - The nature of sol-gel transition

AU - Kuznetsov, Nikita M.

AU - Belousov, Sergey I.

AU - Bakirov, Artem V.

AU - Chvalun, Sergei N.

AU - Kamyshinsky, Roman A.

AU - Mikhutkin, Alexey A.

AU - Vasiliev, Alexander L.

AU - Tolstoy, Peter M.

AU - Mazur, Anton S.

AU - Eidelman, Eugeny D.

AU - Yudina, Elena B.

AU - Vul, Alexander Ya

PY - 2020/5

Y1 - 2020/5

N2 - The paper describes the data on unusual rheological properties of detonation nanodiamonds (DND) hydrosols and presents the fractal model explaining such behavior. The hydrosols of DND with particles size of 4–5 nm and concentration range of 1.1–7.3 wt% with negative (ζ < 0) and positive (ζ > 0) electrokinetic potentials have been studied by rotational viscometry, small-angle X-ray scattering, nuclear magnetic resonance and Cryo Electron Tomography. Remarkable hysteresis of viscosity and thixotropic effect demonstrate the sol-gel transition at very low concentrations of the DND: 4–5 wt% for ζ > 0 and 5–6 wt% for ζ < 0. The transition is accompanied by increase of loss (viscosity) modulus by two orders of magnitude and the storage (elasticity) modulus started to be detected also. The experimental results have been explained in the frame of percolation theory based on the network formation due to faceted DND particles interactions.

AB - The paper describes the data on unusual rheological properties of detonation nanodiamonds (DND) hydrosols and presents the fractal model explaining such behavior. The hydrosols of DND with particles size of 4–5 nm and concentration range of 1.1–7.3 wt% with negative (ζ < 0) and positive (ζ > 0) electrokinetic potentials have been studied by rotational viscometry, small-angle X-ray scattering, nuclear magnetic resonance and Cryo Electron Tomography. Remarkable hysteresis of viscosity and thixotropic effect demonstrate the sol-gel transition at very low concentrations of the DND: 4–5 wt% for ζ > 0 and 5–6 wt% for ζ < 0. The transition is accompanied by increase of loss (viscosity) modulus by two orders of magnitude and the storage (elasticity) modulus started to be detected also. The experimental results have been explained in the frame of percolation theory based on the network formation due to faceted DND particles interactions.

KW - Detonation nanodiamond

KW - Hysteresis of viscosity

KW - Percolation threshold

KW - Rheological properties

KW - Sol-gel transition

KW - Thixotropy

KW - NANO

KW - SMALL-ANGLE SCATTERING

UR - http://www.scopus.com/inward/record.url?scp=85078930111&partnerID=8YFLogxK

UR - https://www.mendeley.com/catalogue/2170af6a-6fd4-3df0-9784-75b5ef65fbd3/

U2 - 10.1016/j.carbon.2020.01.054

DO - 10.1016/j.carbon.2020.01.054

M3 - Article

AN - SCOPUS:85078930111

VL - 161

SP - 486

EP - 494

JO - Carbon

JF - Carbon

SN - 0008-6223

ER -

ID: 53584935