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Unexpected differences in the reactivity between the phosphorus and arsenic derivatives [(CpBIGFe)2(μ,η4:4-E4)] (E = P and As). / Heinl, S.; Timoshkin, A. Y.; Müller, J.; Scheer, M.

в: Chemical Communications, Том 54, № 18, 04.03.2018, стр. 2244-2247.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

Harvard

Heinl, S, Timoshkin, AY, Müller, J & Scheer, M 2018, 'Unexpected differences in the reactivity between the phosphorus and arsenic derivatives [(CpBIGFe)2(μ,η4:4-E4)] (E = P and As)', Chemical Communications, Том. 54, № 18, стр. 2244-2247. https://doi.org/10.1039/c7cc09730a

APA

Heinl, S., Timoshkin, A. Y., Müller, J., & Scheer, M. (2018). Unexpected differences in the reactivity between the phosphorus and arsenic derivatives [(CpBIGFe)2(μ,η4:4-E4)] (E = P and As). Chemical Communications, 54(18), 2244-2247. https://doi.org/10.1039/c7cc09730a

Vancouver

Heinl S, Timoshkin AY, Müller J, Scheer M. Unexpected differences in the reactivity between the phosphorus and arsenic derivatives [(CpBIGFe)2(μ,η4:4-E4)] (E = P and As). Chemical Communications. 2018 Март 4;54(18):2244-2247. https://doi.org/10.1039/c7cc09730a

Author

Heinl, S. ; Timoshkin, A. Y. ; Müller, J. ; Scheer, M. / Unexpected differences in the reactivity between the phosphorus and arsenic derivatives [(CpBIGFe)2(μ,η4:4-E4)] (E = P and As). в: Chemical Communications. 2018 ; Том 54, № 18. стр. 2244-2247.

BibTeX

@article{41983d0886f846c9882a8cdadb380827,
title = "Unexpected differences in the reactivity between the phosphorus and arsenic derivatives [(CpBIGFe)2(μ,η4:4-E4)] (E = P and As)",
abstract = "Different reaction pathways were determined between thermolysis and photolysis reactions of the butterfly complex [{CpBIGFe(CO)2}2(μ,η1:1-As4)] (1b). The thermolysis leads to novel arsenic-rich compounds [(CpBIGFe)2(μ,η4:4-As4)] (2b), [(CpBIGFe)3(μ3,η4:4:4-As6)] (4) and [CpBIGFe(η5-As5)] (5), whereas the photolysis of [{CpBIGFe(CO)2}2(μ,η1:1-E4)] (1a: E = P; 1b: E = As) exclusively results in the decarbonylation products [(CpBIGFe)2(μ,η4:4-P4)] (2a), 2b and [(CpBIGFe)(μ,η4:1-As4)(CpBIGFe(CO)2)] (3). The E4 complexes 2a and 2b show unique structural differences in the solid state despite their related compositions.",
keywords = "COORDINATION SPHERE, IRON COMPLEXES, P-4 ACTIVATION, LIGANDS, TRANSFORMATION, PATHWAY, CLUSTER, ANIONS, AS-6, UNIT",
author = "S. Heinl and Timoshkin, {A. Y.} and J. M{\"u}ller and M. Scheer",
year = "2018",
month = mar,
day = "4",
doi = "10.1039/c7cc09730a",
language = "English",
volume = "54",
pages = "2244--2247",
journal = "Chemical Communications",
issn = "1359-7345",
publisher = "Royal Society of Chemistry",
number = "18",

}

RIS

TY - JOUR

T1 - Unexpected differences in the reactivity between the phosphorus and arsenic derivatives [(CpBIGFe)2(μ,η4:4-E4)] (E = P and As)

AU - Heinl, S.

AU - Timoshkin, A. Y.

AU - Müller, J.

AU - Scheer, M.

PY - 2018/3/4

Y1 - 2018/3/4

N2 - Different reaction pathways were determined between thermolysis and photolysis reactions of the butterfly complex [{CpBIGFe(CO)2}2(μ,η1:1-As4)] (1b). The thermolysis leads to novel arsenic-rich compounds [(CpBIGFe)2(μ,η4:4-As4)] (2b), [(CpBIGFe)3(μ3,η4:4:4-As6)] (4) and [CpBIGFe(η5-As5)] (5), whereas the photolysis of [{CpBIGFe(CO)2}2(μ,η1:1-E4)] (1a: E = P; 1b: E = As) exclusively results in the decarbonylation products [(CpBIGFe)2(μ,η4:4-P4)] (2a), 2b and [(CpBIGFe)(μ,η4:1-As4)(CpBIGFe(CO)2)] (3). The E4 complexes 2a and 2b show unique structural differences in the solid state despite their related compositions.

AB - Different reaction pathways were determined between thermolysis and photolysis reactions of the butterfly complex [{CpBIGFe(CO)2}2(μ,η1:1-As4)] (1b). The thermolysis leads to novel arsenic-rich compounds [(CpBIGFe)2(μ,η4:4-As4)] (2b), [(CpBIGFe)3(μ3,η4:4:4-As6)] (4) and [CpBIGFe(η5-As5)] (5), whereas the photolysis of [{CpBIGFe(CO)2}2(μ,η1:1-E4)] (1a: E = P; 1b: E = As) exclusively results in the decarbonylation products [(CpBIGFe)2(μ,η4:4-P4)] (2a), 2b and [(CpBIGFe)(μ,η4:1-As4)(CpBIGFe(CO)2)] (3). The E4 complexes 2a and 2b show unique structural differences in the solid state despite their related compositions.

KW - COORDINATION SPHERE

KW - IRON COMPLEXES

KW - P-4 ACTIVATION

KW - LIGANDS

KW - TRANSFORMATION

KW - PATHWAY

KW - CLUSTER

KW - ANIONS

KW - AS-6

KW - UNIT

UR - http://www.scopus.com/inward/record.url?scp=85042647610&partnerID=8YFLogxK

UR - http://xlink.rsc.org/?DOI=C7CC09730A

UR - http://www.mendeley.com/research/unexpected-differences-reactivity-between-phosphorus-arsenic-derivatives-cp-supbigsup-fe-sub2sub-%CE%BC%CE%B7

U2 - 10.1039/c7cc09730a

DO - 10.1039/c7cc09730a

M3 - Article

AN - SCOPUS:85042647610

VL - 54

SP - 2244

EP - 2247

JO - Chemical Communications

JF - Chemical Communications

SN - 1359-7345

IS - 18

ER -

ID: 17371118