Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Ultradisperse Pt nanoparticles anchored on defect sites in oxygen-free few-layer graphene and their catalytic properties in CO oxidation. / Grayfer, Ekaterina D.; Kibis, Lidiya S.; Stadnichenko, Andrey I.; Vilkov, Oleg Yu; Boronin, Andrei I.; Slavinskaya, Elena M.; Stonkus, Olga A.; Fedorov, Vladimir E.
в: Carbon, Том 89, 2015, стр. 290-299.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Ultradisperse Pt nanoparticles anchored on defect sites in oxygen-free few-layer graphene and their catalytic properties in CO oxidation
AU - Grayfer, Ekaterina D.
AU - Kibis, Lidiya S.
AU - Stadnichenko, Andrey I.
AU - Vilkov, Oleg Yu
AU - Boronin, Andrei I.
AU - Slavinskaya, Elena M.
AU - Stonkus, Olga A.
AU - Fedorov, Vladimir E.
PY - 2015
Y1 - 2015
N2 - Highly uniform and crystalline ultradisperse Pt nanoparticles with average sizes of 2.4 nm were deposited on oxygen-free few-layer graphene (FLG) by polyol reduction method without any additional protective agents. The samples were analyzed by Raman spectroscopy, photoelectron spectroscopy using synchrotron radiation and high-resolution transmission electron microscopy. The experiments showed that metal nanoparticles were mostly stabilized at defect sites of the FLG support in the absence of oxygen functionalities. Catalytic properties of the samples were tested in CO oxidation reaction. For Pt nanoparticles forming agglomerates an oscillatory behavior under catalytic reaction conditions was observed for the first time for metal-graphene catalysts.
AB - Highly uniform and crystalline ultradisperse Pt nanoparticles with average sizes of 2.4 nm were deposited on oxygen-free few-layer graphene (FLG) by polyol reduction method without any additional protective agents. The samples were analyzed by Raman spectroscopy, photoelectron spectroscopy using synchrotron radiation and high-resolution transmission electron microscopy. The experiments showed that metal nanoparticles were mostly stabilized at defect sites of the FLG support in the absence of oxygen functionalities. Catalytic properties of the samples were tested in CO oxidation reaction. For Pt nanoparticles forming agglomerates an oscillatory behavior under catalytic reaction conditions was observed for the first time for metal-graphene catalysts.
UR - http://www.scopus.com/inward/record.url?scp=84927938735&partnerID=8YFLogxK
U2 - 10.1016/j.carbon.2015.03.050
DO - 10.1016/j.carbon.2015.03.050
M3 - Article
AN - SCOPUS:84927938735
VL - 89
SP - 290
EP - 299
JO - Carbon
JF - Carbon
SN - 0008-6223
ER -
ID: 9290917