Результаты исследований: Научные публикации в периодических изданиях › статья
Two complexes of Pt-IV and Au-III with 2,2 '-dipyridylamine and 2,2 '-dipyridylaminide ligands. / Chernyshev, A.N.; Kukushkin, V.Y.; Haukka, M.
в: Acta Crystallographica Section C-Structural Chemistry, Том 70, № 12, 2014, стр. 1133-1137.Результаты исследований: Научные публикации в периодических изданиях › статья
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TY - JOUR
T1 - Two complexes of Pt-IV and Au-III with 2,2 '-dipyridylamine and 2,2 '-dipyridylaminide ligands
AU - Chernyshev, A.N.
AU - Kukushkin, V.Y.
AU - Haukka, M.
PY - 2014
Y1 - 2014
N2 - © 2014 International Union of Crystallography. Two noble metal complexes involving ancillary chloride ligands and chelating 2,2′-bipyridylamine (Hdpa) or its deprotonated derivative (dpa), namely [bis(pyridin-2-yl-κN)amine]tetrachloridoplatinum(IV), [PtCl4(C10H9N3)], and [bis(pyridin-2-yl-κN)aminido]dichloridogold(III), [AuCl2(C10H8N3)], are presented and structurally characterized. The metal atom in the former has a slightly distorted octahedral coordination environment, formed by four chloride ligands and two pyridyl N atoms of Hdpa, while the metal atom in the latter has a slightly distorted square-planar coordination environment, formed by two chloride ligands and two pyridyl N atoms of dpa. The difference in conjugation between the pyridine rings in normal and deprotonated 2,2′-dipyridylamine is discussed on the basis of the structural features of these complexes. The influence of weak interactions on the supramolecul
AB - © 2014 International Union of Crystallography. Two noble metal complexes involving ancillary chloride ligands and chelating 2,2′-bipyridylamine (Hdpa) or its deprotonated derivative (dpa), namely [bis(pyridin-2-yl-κN)amine]tetrachloridoplatinum(IV), [PtCl4(C10H9N3)], and [bis(pyridin-2-yl-κN)aminido]dichloridogold(III), [AuCl2(C10H8N3)], are presented and structurally characterized. The metal atom in the former has a slightly distorted octahedral coordination environment, formed by four chloride ligands and two pyridyl N atoms of Hdpa, while the metal atom in the latter has a slightly distorted square-planar coordination environment, formed by two chloride ligands and two pyridyl N atoms of dpa. The difference in conjugation between the pyridine rings in normal and deprotonated 2,2′-dipyridylamine is discussed on the basis of the structural features of these complexes. The influence of weak interactions on the supramolecul
U2 - 10.1107/S2053229614021548
DO - 10.1107/S2053229614021548
M3 - Article
VL - 70
SP - 1133
EP - 1137
JO - Acta Crystallographica Section C-Structural Chemistry
JF - Acta Crystallographica Section C-Structural Chemistry
SN - 2053-2296
IS - 12
ER -
ID: 7037396