TY - JOUR

T1 - Transport properties of superionic crystals with tysonite structure

AU - Murin, I. V.

AU - Fujara, F.

AU - Glumov, O. V.

AU - Privalov, A. F.

AU - Vieth, H. M.

PY - 1997/12/1

Y1 - 1997/12/1

N2 - Transport properties of superionic conductors with a tysonite-type structure have been investigated by impedance spectroscopy, 19F NMR, high hydrostatic pressure and radio tracer (36Cl) techniques. It is demonstrated that these experimental methods are powerful tools to clarify ionic processes on the microscopic level in investigated solid electrolytes with predominant fluorine mobility. Correlation between transport properties and structural data were established.

AB - Transport properties of superionic conductors with a tysonite-type structure have been investigated by impedance spectroscopy, 19F NMR, high hydrostatic pressure and radio tracer (36Cl) techniques. It is demonstrated that these experimental methods are powerful tools to clarify ionic processes on the microscopic level in investigated solid electrolytes with predominant fluorine mobility. Correlation between transport properties and structural data were established.

KW - F NMR Cl-Diffusion

KW - Electroconductivity

KW - Fluoride-Tysonite

KW - Ionic Transport

KW - Solid Electrolyte

UR - http://www.scopus.com/inward/record.url?scp=4143057002&partnerID=8YFLogxK

M3 - Article

AN - SCOPUS:4143057002

VL - 239-241

SP - 407

EP - 412

JO - Materials Science Forum

JF - Materials Science Forum

SN - 0255-5476

ER -