Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Transformation of the electronic structure of fullerene C60 caused by complex formation in N-methylpyrrolidone solutions. / Biryulin, Yu F.; Evlampieva, N. P.; Melenevskaya, E. Yu; Bocharov, V. N.; Zgonnik, V. N.; Ryumtsev, E. I.
в: Technical Physics Letters, Том 26, № 8, 08.2000, стр. 662-665.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Transformation of the electronic structure of fullerene C60 caused by complex formation in N-methylpyrrolidone solutions
AU - Biryulin, Yu F.
AU - Evlampieva, N. P.
AU - Melenevskaya, E. Yu
AU - Bocharov, V. N.
AU - Zgonnik, V. N.
AU - Ryumtsev, E. I.
N1 - Funding Information: This work was supported by the Russian Interdisciplinary Scientific–Technical Program “Fullerenes and Atomic Clusters” (project no. 98076) and the Russian Federal Program “Integration” (project no. 7-326.38).
PY - 2000/8
Y1 - 2000/8
N2 - Evolution of the electronic absorption and photoluminescence spectra of the fullerene C60 solutions with various concentrations in a polar solvent (N-methylpyrrolidone) was studied. Comparison with the electrooptical properties of these solutions shows that a slow (associative) fullerene-solvent interaction mechanism is operative at large (nearly saturating) concentrations (1 × 10-3 g/cm3), whereas the solutions of relatively low concentration (less than 5 × 10-4 g/cm3) exhibit fast complex formation between fullerene and the solvent molecules. The latter interaction significantly changes the electronic structure of fullerene.
AB - Evolution of the electronic absorption and photoluminescence spectra of the fullerene C60 solutions with various concentrations in a polar solvent (N-methylpyrrolidone) was studied. Comparison with the electrooptical properties of these solutions shows that a slow (associative) fullerene-solvent interaction mechanism is operative at large (nearly saturating) concentrations (1 × 10-3 g/cm3), whereas the solutions of relatively low concentration (less than 5 × 10-4 g/cm3) exhibit fast complex formation between fullerene and the solvent molecules. The latter interaction significantly changes the electronic structure of fullerene.
UR - http://www.scopus.com/inward/record.url?scp=0034238262&partnerID=8YFLogxK
U2 - 10.1134/1.1307806
DO - 10.1134/1.1307806
M3 - Article
AN - SCOPUS:0034238262
VL - 26
SP - 662
EP - 665
JO - Technical Physics Letters
JF - Technical Physics Letters
SN - 1063-7850
IS - 8
ER -
ID: 94256093