Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Topological Isomorphism of Liquid–Vapor, Fusibility, and Solubility Diagrams: Analogues of Gibbs–Konovalov and Gibbs–Roozeboom Laws for Solubility Diagrams. / Чарыков, Николай Александрович ; Румянцев, А. В.; Семёнов, Константин Николаевич; Шаймарданов, Жасулан Кудайбергенович; Шаймарданова, Ботагоз; Куленова, Н. А.; Саденова, М. А.; Шушкевич, Л. В.; Кескинов, Виктор Анатольевич; Блохин, Александр Андреевич.
в: Processes, Том 11, № 5, 1405, 06.05.2023.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Topological Isomorphism of Liquid–Vapor, Fusibility, and Solubility Diagrams: Analogues of Gibbs–Konovalov and Gibbs–Roozeboom Laws for Solubility Diagrams
AU - Чарыков, Николай Александрович
AU - Румянцев, А. В.
AU - Семёнов, Константин Николаевич
AU - Шаймарданов, Жасулан Кудайбергенович
AU - Шаймарданова, Ботагоз
AU - Куленова, Н. А.
AU - Саденова, М. А.
AU - Шушкевич, Л. В.
AU - Кескинов, Виктор Анатольевич
AU - Блохин, Александр Андреевич
PY - 2023/5/6
Y1 - 2023/5/6
N2 - The comprehensive topological isomorphism of liquid–vapor, fusibility, and solubility diagrams in the proper sets of variables is proven with the aid of van der Waals equations of the shift in phase equilibrium. Analogues of Gibbs–Konovalov and Gibbs–Roozeboom laws are demonstrated in solubility diagrams of ternary and quaternary systems under crystallization of different types of solid solutions. For the demonstration, the quaternary reciprocal system (Formula presented.) and its ternary subsystems with modeling of the liquid phase within the framework of the classical Pitzer formalism are mainly used. An algorithm for calculating solubility equilibria in these systems is given.
AB - The comprehensive topological isomorphism of liquid–vapor, fusibility, and solubility diagrams in the proper sets of variables is proven with the aid of van der Waals equations of the shift in phase equilibrium. Analogues of Gibbs–Konovalov and Gibbs–Roozeboom laws are demonstrated in solubility diagrams of ternary and quaternary systems under crystallization of different types of solid solutions. For the demonstration, the quaternary reciprocal system (Formula presented.) and its ternary subsystems with modeling of the liquid phase within the framework of the classical Pitzer formalism are mainly used. An algorithm for calculating solubility equilibria in these systems is given.
KW - Gibbs–Konovalov laws
KW - Gibbs–Roozeboom rules
KW - alyotrope
KW - incomplete Gibbs potential metric
KW - phase diagram topological isomorphism
KW - reciprocal solid solutions
UR - https://www.mendeley.com/catalogue/dc0dd343-e080-3a6c-b3e2-1670ffa9c28a/
U2 - 10.3390/pr11051405
DO - 10.3390/pr11051405
M3 - Article
VL - 11
JO - Processes
JF - Processes
SN - 2227-9717
IS - 5
M1 - 1405
ER -
ID: 113806552