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Three Fluorinated Trityl Alcohols and their Lithium Salts – Synthesis, Molecular Structures, and Acidity. / Kögel, Julius Fritz ; Lork, Enno ; Lõkov, Märt ; Parman, Elisabeth; Leito, Ivo ; Timoshkin, Alexey Y. ; Beckmann, Jens .

в: European Journal of Inorganic Chemistry, Том 2019, № 31, 25.08.2019, стр. 3612-3618.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

Harvard

Kögel, JF, Lork, E, Lõkov, M, Parman, E, Leito, I, Timoshkin, AY & Beckmann, J 2019, 'Three Fluorinated Trityl Alcohols and their Lithium Salts – Synthesis, Molecular Structures, and Acidity', European Journal of Inorganic Chemistry, Том. 2019, № 31, стр. 3612-3618. https://doi.org/10.1002/ejic.201900603

APA

Kögel, J. F., Lork, E., Lõkov, M., Parman, E., Leito, I., Timoshkin, A. Y., & Beckmann, J. (2019). Three Fluorinated Trityl Alcohols and their Lithium Salts – Synthesis, Molecular Structures, and Acidity. European Journal of Inorganic Chemistry, 2019(31), 3612-3618. https://doi.org/10.1002/ejic.201900603

Vancouver

Kögel JF, Lork E, Lõkov M, Parman E, Leito I, Timoshkin AY и пр. Three Fluorinated Trityl Alcohols and their Lithium Salts – Synthesis, Molecular Structures, and Acidity. European Journal of Inorganic Chemistry. 2019 Авг. 25;2019(31):3612-3618. https://doi.org/10.1002/ejic.201900603

Author

Kögel, Julius Fritz ; Lork, Enno ; Lõkov, Märt ; Parman, Elisabeth ; Leito, Ivo ; Timoshkin, Alexey Y. ; Beckmann, Jens . / Three Fluorinated Trityl Alcohols and their Lithium Salts – Synthesis, Molecular Structures, and Acidity. в: European Journal of Inorganic Chemistry. 2019 ; Том 2019, № 31. стр. 3612-3618.

BibTeX

@article{9ad0617c53364a7d8f7e0ecdbda2b753,
title = "Three Fluorinated Trityl Alcohols and their Lithium Salts – Synthesis, Molecular Structures, and Acidity",
abstract = "The fluorinated trityl alcohols (C6F5)3COH, (C6H2F3)3COH and (C6(CF3)2H3)3COH were prepared in good to excellent yields by a facile one‐step procedure. These alcohols and their lithium salts were fully characterized by NMR and IR spectroscopy, mass spectrometry and XRD analysis. The molecular structures reveal that the differences in the fluorination patterns result in a divergent coordination behavior in their lithium salts. Experimental and computational studies concerning the acidity show similar electron withdrawing character of the substituents and disclose acidity properties in the range of phenols.",
keywords = "Acidity, Alcohols, Density functional calculations, Fluorinated ligands, O ligands, ANIONS, COORDINATION CHEMISTRY, ALKOXIDE, COMPLEXES, FEATURES, AGOC(CF3)(3), SCALE, BASIS-SET, DERIVATIVES",
author = "K{\"o}gel, {Julius Fritz} and Enno Lork and M{\"a}rt L{\~o}kov and Elisabeth Parman and Ivo Leito and Timoshkin, {Alexey Y.} and Jens Beckmann",
note = "Publisher Copyright: {\textcopyright} 2019 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA.",
year = "2019",
month = aug,
day = "25",
doi = "10.1002/ejic.201900603",
language = "English",
volume = "2019",
pages = "3612--3618",
journal = "Berichte der deutschen chemischen Gesellschaft",
issn = "0365-9496",
publisher = "Wiley-Blackwell",
number = "31",

}

RIS

TY - JOUR

T1 - Three Fluorinated Trityl Alcohols and their Lithium Salts – Synthesis, Molecular Structures, and Acidity

AU - Kögel, Julius Fritz

AU - Lork, Enno

AU - Lõkov, Märt

AU - Parman, Elisabeth

AU - Leito, Ivo

AU - Timoshkin, Alexey Y.

AU - Beckmann, Jens

N1 - Publisher Copyright: © 2019 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA.

PY - 2019/8/25

Y1 - 2019/8/25

N2 - The fluorinated trityl alcohols (C6F5)3COH, (C6H2F3)3COH and (C6(CF3)2H3)3COH were prepared in good to excellent yields by a facile one‐step procedure. These alcohols and their lithium salts were fully characterized by NMR and IR spectroscopy, mass spectrometry and XRD analysis. The molecular structures reveal that the differences in the fluorination patterns result in a divergent coordination behavior in their lithium salts. Experimental and computational studies concerning the acidity show similar electron withdrawing character of the substituents and disclose acidity properties in the range of phenols.

AB - The fluorinated trityl alcohols (C6F5)3COH, (C6H2F3)3COH and (C6(CF3)2H3)3COH were prepared in good to excellent yields by a facile one‐step procedure. These alcohols and their lithium salts were fully characterized by NMR and IR spectroscopy, mass spectrometry and XRD analysis. The molecular structures reveal that the differences in the fluorination patterns result in a divergent coordination behavior in their lithium salts. Experimental and computational studies concerning the acidity show similar electron withdrawing character of the substituents and disclose acidity properties in the range of phenols.

KW - Acidity

KW - Alcohols

KW - Density functional calculations

KW - Fluorinated ligands

KW - O ligands

KW - ANIONS

KW - COORDINATION CHEMISTRY

KW - ALKOXIDE

KW - COMPLEXES

KW - FEATURES

KW - AGOC(CF3)(3)

KW - SCALE

KW - BASIS-SET

KW - DERIVATIVES

UR - http://www.scopus.com/inward/record.url?scp=85070751191&partnerID=8YFLogxK

UR - http://www.mendeley.com/research/three-fluorinated-trityl-alcohols-lithium-salts-synthesis-molecular-structures-acidity

U2 - 10.1002/ejic.201900603

DO - 10.1002/ejic.201900603

M3 - Article

VL - 2019

SP - 3612

EP - 3618

JO - Berichte der deutschen chemischen Gesellschaft

JF - Berichte der deutschen chemischen Gesellschaft

SN - 0365-9496

IS - 31

ER -

ID: 44930272