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Thermodynamics of gaseous cobaltates CaCoO2, SrCoO2 and BaCoO2. / Shugurov, S. M.; Lopatin, S. I.

в: Journal of Chemical Thermodynamics, Том 37, № 7, 01.07.2005, стр. 715-719.

Результаты исследований: Научные публикации в периодических изданияхстатьяРецензирование

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Shugurov, S. M. ; Lopatin, S. I. / Thermodynamics of gaseous cobaltates CaCoO2, SrCoO2 and BaCoO2. в: Journal of Chemical Thermodynamics. 2005 ; Том 37, № 7. стр. 715-719.

BibTeX

@article{96e4fc9bf29f47c9a6cfcc22a5eea7ab,
title = "Thermodynamics of gaseous cobaltates CaCoO2, SrCoO2 and BaCoO2",
abstract = "The existence of gaseous cobaltates of alkaline-earth metals was established in the present work by high-temperature mass spectrometry. Gaseous molecules: CaCoO2, SrCoO2 and BaCoO2 have been found for the first time. On the basis of the measured constants of the equilibrium of gas-phase reactions the standard enthalpies of formation: (-149 ± 19) kJ · mol-1, (-149 ± 20) kJ · mol-1 and (-250 ± 16) kJ · mol-1; and standard atomization enthalpies: (1251 ± 22) kJ · mol -1, (1233 ± 23) kJ · mol-1 and (1353 ± 20) kJ · mol-1 for CaCoO2, SrCoO 2 and BaCoO2, respectively, have been defined.",
keywords = "Alkaline-earth metals cobaltates, BaCoO, CaCoO, Gaseous oxyacid salts, Knudsen cell/mass spectrometry, SrCoO, Thermodynamic functions",
author = "Shugurov, {S. M.} and Lopatin, {S. I.}",
year = "2005",
month = jul,
day = "1",
doi = "10.1016/j.jct.2004.08.014",
language = "English",
volume = "37",
pages = "715--719",
journal = "Journal of Chemical Thermodynamics",
issn = "0021-9614",
publisher = "Elsevier",
number = "7",

}

RIS

TY - JOUR

T1 - Thermodynamics of gaseous cobaltates CaCoO2, SrCoO2 and BaCoO2

AU - Shugurov, S. M.

AU - Lopatin, S. I.

PY - 2005/7/1

Y1 - 2005/7/1

N2 - The existence of gaseous cobaltates of alkaline-earth metals was established in the present work by high-temperature mass spectrometry. Gaseous molecules: CaCoO2, SrCoO2 and BaCoO2 have been found for the first time. On the basis of the measured constants of the equilibrium of gas-phase reactions the standard enthalpies of formation: (-149 ± 19) kJ · mol-1, (-149 ± 20) kJ · mol-1 and (-250 ± 16) kJ · mol-1; and standard atomization enthalpies: (1251 ± 22) kJ · mol -1, (1233 ± 23) kJ · mol-1 and (1353 ± 20) kJ · mol-1 for CaCoO2, SrCoO 2 and BaCoO2, respectively, have been defined.

AB - The existence of gaseous cobaltates of alkaline-earth metals was established in the present work by high-temperature mass spectrometry. Gaseous molecules: CaCoO2, SrCoO2 and BaCoO2 have been found for the first time. On the basis of the measured constants of the equilibrium of gas-phase reactions the standard enthalpies of formation: (-149 ± 19) kJ · mol-1, (-149 ± 20) kJ · mol-1 and (-250 ± 16) kJ · mol-1; and standard atomization enthalpies: (1251 ± 22) kJ · mol -1, (1233 ± 23) kJ · mol-1 and (1353 ± 20) kJ · mol-1 for CaCoO2, SrCoO 2 and BaCoO2, respectively, have been defined.

KW - Alkaline-earth metals cobaltates

KW - BaCoO

KW - CaCoO

KW - Gaseous oxyacid salts

KW - Knudsen cell/mass spectrometry

KW - SrCoO

KW - Thermodynamic functions

UR - http://www.scopus.com/inward/record.url?scp=19944403599&partnerID=8YFLogxK

U2 - 10.1016/j.jct.2004.08.014

DO - 10.1016/j.jct.2004.08.014

M3 - Article

AN - SCOPUS:19944403599

VL - 37

SP - 715

EP - 719

JO - Journal of Chemical Thermodynamics

JF - Journal of Chemical Thermodynamics

SN - 0021-9614

IS - 7

ER -

ID: 40770001