Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Thermodynamics of dispergation : Development of Rehbinder's ideas. / Rusanov, A. I.
в: Colloids and Surfaces A: Physicochemical and Engineering Aspects, Том 160, № 2, 12.1999, стр. 79-87.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Thermodynamics of dispergation
T2 - Development of Rehbinder's ideas
AU - Rusanov, A. I.
N1 - Funding Information: This work has been done under the financial support of Russian Foundation of Basic Research (Grants # 96-15-97312 and 98-03-32009a).
PY - 1999/12
Y1 - 1999/12
N2 - Statistical-mechanical expressions for the chemical potential of a dispersed particle, for the Gibbs energy of dispergation, and for the activation energy of dispergation are derived for a monodisperse system with a liquid continuous medium and a solid or liquid dispersed phase. The work of dispergation is calculated as a function of the size of dispersed particles with taking into account the dependence of surface free energy on the particle size and the interaction between particles in the form of the hard sphere potential. The boundary of the region of spontaneous dispergation and the condition for the realisation of stable states in the process of dispergation are formulated. Copyright (C) 1999 Elsevier Science B.V.
AB - Statistical-mechanical expressions for the chemical potential of a dispersed particle, for the Gibbs energy of dispergation, and for the activation energy of dispergation are derived for a monodisperse system with a liquid continuous medium and a solid or liquid dispersed phase. The work of dispergation is calculated as a function of the size of dispersed particles with taking into account the dependence of surface free energy on the particle size and the interaction between particles in the form of the hard sphere potential. The boundary of the region of spontaneous dispergation and the condition for the realisation of stable states in the process of dispergation are formulated. Copyright (C) 1999 Elsevier Science B.V.
KW - Activation energy of dispergation
KW - Chemical potentials of dispersed particles
KW - Spontaneous dispergation
KW - Thermodynamics of dispergation
KW - Work of dispergation
UR - http://www.scopus.com/inward/record.url?scp=0032700591&partnerID=8YFLogxK
U2 - 10.1016/S0927-7757(99)00353-2
DO - 10.1016/S0927-7757(99)00353-2
M3 - Article
AN - SCOPUS:0032700591
VL - 160
SP - 79
EP - 87
JO - Colloids and Surfaces A: Physicochemical and Engineering Aspects
JF - Colloids and Surfaces A: Physicochemical and Engineering Aspects
SN - 0927-7757
IS - 2
ER -
ID: 95719045