TY - JOUR

T1 - Thermodynamics of a Liquid Wetting Film on a Spherical Particle with an Adsorbed Ion

AU - Warshavsky, V.B.

AU - Podguzova, T.S.

AU - Tatyanenko, D.V.

AU - Shchekin, A.K.

PY - 2013

Y1 - 2013

N2 - A thermodynamic description has been formulated for a wetting film formed on a spherical solid dielectric particle with a discrete electric charge adsorbed on its surface. The description is based on differential equations for the equilibrium nonspherical profile of the film and electric potentials in the particle, film, and a vapor–gas medium. By combining these equations and taking into account the action of disjoining pressure in the film, the film shape in a noncentral electric field has been determined and an expression has been derived for the chemical potential of condensate molecules in the film as a function of the effective curvature radius of the film external surface, this radius being predetermined by the number of condensate molecules in the film. The magnitude of the adsorbed electric charge, its characteristic size and its location with respect to the center of the solid particle, dielectric permittivities of the liquid in the film and the material of the particle, particle size, and the chara

AB - A thermodynamic description has been formulated for a wetting film formed on a spherical solid dielectric particle with a discrete electric charge adsorbed on its surface. The description is based on differential equations for the equilibrium nonspherical profile of the film and electric potentials in the particle, film, and a vapor–gas medium. By combining these equations and taking into account the action of disjoining pressure in the film, the film shape in a noncentral electric field has been determined and an expression has been derived for the chemical potential of condensate molecules in the film as a function of the effective curvature radius of the film external surface, this radius being predetermined by the number of condensate molecules in the film. The magnitude of the adsorbed electric charge, its characteristic size and its location with respect to the center of the solid particle, dielectric permittivities of the liquid in the film and the material of the particle, particle size, and the chara

U2 - 10.1134/S1061933X13050153

DO - 10.1134/S1061933X13050153

M3 - Article

VL - 75

SP - 504

EP - 513

JO - Colloid Journal

JF - Colloid Journal

SN - 1061-933X

IS - 5

ER -