Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Thermodynamic study of gaseous manganese phosphates MnPO3 and MnPO2. / Shugurov, S. M.; Timoshkin, A. Yu; Lopatin, S. I.
в: Phosphorus, Sulfur and Silicon and the Related Elements, Том 179, № 10, 10.2004, стр. 2091-2098.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Thermodynamic study of gaseous manganese phosphates MnPO3 and MnPO2
AU - Shugurov, S. M.
AU - Timoshkin, A. Yu
AU - Lopatin, S. I.
PY - 2004/10
Y1 - 2004/10
N2 - In the present work, the stability of gaseous manganese-containing salts was proved by the high-temperature mass spectrometric method. New previously unreported species were found, MnPO3 and MnPO2. On the basis of equilibrium constants measured for gas-phase reactions the standard formation enthalpies for MnPO3 and MnPO2 were determined as -602.0 ± 10.0 kJ/mole and -299.0 ± 11.5 kJ/mole, respectively, and the standard atomization enthalpies as 1950 ± 14 kJ/mole and 1397 ± 14 kJ/mole, respectively.
AB - In the present work, the stability of gaseous manganese-containing salts was proved by the high-temperature mass spectrometric method. New previously unreported species were found, MnPO3 and MnPO2. On the basis of equilibrium constants measured for gas-phase reactions the standard formation enthalpies for MnPO3 and MnPO2 were determined as -602.0 ± 10.0 kJ/mole and -299.0 ± 11.5 kJ/mole, respectively, and the standard atomization enthalpies as 1950 ± 14 kJ/mole and 1397 ± 14 kJ/mole, respectively.
KW - Ab initio computations
KW - Double two-temperature cell
KW - Gaseous manganese phosphates
KW - High-temperature mass spectrometry
KW - MnPO
KW - Thermodynamic functions
UR - http://www.scopus.com/inward/record.url?scp=7744223892&partnerID=8YFLogxK
U2 - 10.1080/10426500490474950
DO - 10.1080/10426500490474950
M3 - Article
AN - SCOPUS:7744223892
VL - 179
SP - 2091
EP - 2098
JO - Phosphorus, Sulfur and Silicon and the Related Elements
JF - Phosphorus, Sulfur and Silicon and the Related Elements
SN - 1042-6507
IS - 10
ER -
ID: 17373416