Thermodynamic properties of gaseous cerium phosphate studied by Knudsen effusion mass spectrometry.

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Thermodynamic properties of gaseous cerium phosphate studied by Knudsen effusion mass spectrometry. / Лопатин, Сергей Игоревич ; Шугуров, Сергей Михайлович ; Панин, Андрей Иванович.

в: Journal of Mass Spectrometry, Том 54, № 6, 06.2019, стр. 507-519.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

BibTeX

@article{9c264953162e49bab3f48de588bc7baf,

title = "Thermodynamic properties of gaseous cerium phosphate studied by Knudsen effusion mass spectrometry.",

abstract = "Gaseous CePO 2 has been identified by Knudsen effusion mass spectrometry during vaporization of CeO 2 and magnesium diphosphate from tungsten double, two-temperature effusion cell. Structure and molecular parameters of gaseous cerium phosphate under study were determined using quantum chemical calculations. On the basis of equilibrium constants measured for gas-phase reaction, standard formation enthalpy of CePO 2 was determined to be −508 ± 41 kJ ⋅ mol −1 at the temperature 298 K. ",

keywords = "Knudsen effusion mass spectrometry, ab initio calculations, double, two-temperature cell, gaseous cerium phosphate CePO, thermodynamic properties, gaseous cerium phosphate CePO2, THERMAL-STABILITY, two-temperature cell, ENERGY, double, HIGH-TEMPERATURE, SALTS, MOLECULES, OXYGEN-CONTAINING ACIDS, VAPORIZATION, IONIZATION CROSS-SECTIONS",

author = "Лопатин, {Сергей Игоревич} and Шугуров, {Сергей Михайлович} and Панин, {Андрей Иванович}",

year = "2019",

month = jun,

doi = "10.1002/jms.4358",

language = "English",

volume = "54",

pages = "507--519",

journal = "Journal of Mass Spectrometry",

issn = "1076-5174",

publisher = "Wiley-Blackwell",

number = "6",

}

RIS

TY - JOUR

T1 - Thermodynamic properties of gaseous cerium phosphate studied by Knudsen effusion mass spectrometry.

AU - Лопатин, Сергей Игоревич

AU - Шугуров, Сергей Михайлович

AU - Панин, Андрей Иванович

PY - 2019/6

Y1 - 2019/6

N2 - Gaseous CePO 2 has been identified by Knudsen effusion mass spectrometry during vaporization of CeO 2 and magnesium diphosphate from tungsten double, two-temperature effusion cell. Structure and molecular parameters of gaseous cerium phosphate under study were determined using quantum chemical calculations. On the basis of equilibrium constants measured for gas-phase reaction, standard formation enthalpy of CePO 2 was determined to be −508 ± 41 kJ ⋅ mol −1 at the temperature 298 K.

AB - Gaseous CePO 2 has been identified by Knudsen effusion mass spectrometry during vaporization of CeO 2 and magnesium diphosphate from tungsten double, two-temperature effusion cell. Structure and molecular parameters of gaseous cerium phosphate under study were determined using quantum chemical calculations. On the basis of equilibrium constants measured for gas-phase reaction, standard formation enthalpy of CePO 2 was determined to be −508 ± 41 kJ ⋅ mol −1 at the temperature 298 K.

KW - Knudsen effusion mass spectrometry

KW - ab initio calculations

KW - double, two-temperature cell

KW - gaseous cerium phosphate CePO

KW - thermodynamic properties

KW - gaseous cerium phosphate CePO2

KW - THERMAL-STABILITY

KW - two-temperature cell

KW - ENERGY

KW - double

KW - HIGH-TEMPERATURE

KW - SALTS

KW - MOLECULES

KW - OXYGEN-CONTAINING ACIDS

KW - VAPORIZATION

KW - IONIZATION CROSS-SECTIONS

UR - http://www.scopus.com/inward/record.url?scp=85068050099&partnerID=8YFLogxK

UR - http://www.mendeley.com/research/thermodynamic-properties-gaseous-cerium-phosphate-studied-knudsen-effusion-mass-spectrometry

U2 - 10.1002/jms.4358

DO - 10.1002/jms.4358

M3 - Article

VL - 54

SP - 507

EP - 519

JO - Journal of Mass Spectrometry

JF - Journal of Mass Spectrometry

SN - 1076-5174

IS - 6

ER -

ID: 43511441