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Thermochemistry of solution, solvation and hydrogen bonding of linear and cyclic ethers in solvents. / Rakipov, Ilnaz T.; Semenov, Konstantin N.; Petrov, Artem A.; Akhmadiyarov, Aydar A.; Khachatrian, Artashes A.; Fakhurtdinova, Aliya R.; Solomonov, Boris N.
в: Thermochimica Acta, Том 700, 178932, 01.06.2021.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Thermochemistry of solution, solvation and hydrogen bonding of linear and cyclic ethers in solvents
AU - Rakipov, Ilnaz T.
AU - Semenov, Konstantin N.
AU - Petrov, Artem A.
AU - Akhmadiyarov, Aydar A.
AU - Khachatrian, Artashes A.
AU - Fakhurtdinova, Aliya R.
AU - Solomonov, Boris N.
N1 - Publisher Copyright: © 2021 Copyright: Copyright 2021 Elsevier B.V., All rights reserved.
PY - 2021/6/1
Y1 - 2021/6/1
N2 - In work a thermochemistry of solution, solvation and hydrogen bond formation of linear (diethyl ether and diglyme) and cyclic ethers (1,4-dioxane, 12-crown-4, 15-crown-5 and 18-crown-6) in proton acceptor and proton donor solvents were studied. The infinite dilution solution enthalpies of ethers in cyclohexane, carbon tetrachloride, benzene, ethyl acetate, N,N-dimethylformamide, dimethylsulfoxide, acetone, pyridine, chloroform and methanol were measured at 298.15 K. The solvation and hydrogen bonding enthalpies of ethers in the solvent are calculated. The influence of number of active centers in ethers on thermochemical parameters is shown. It was found that the formation of hydrogen bonds for linear and cyclic ethers with proton donors are different.
AB - In work a thermochemistry of solution, solvation and hydrogen bond formation of linear (diethyl ether and diglyme) and cyclic ethers (1,4-dioxane, 12-crown-4, 15-crown-5 and 18-crown-6) in proton acceptor and proton donor solvents were studied. The infinite dilution solution enthalpies of ethers in cyclohexane, carbon tetrachloride, benzene, ethyl acetate, N,N-dimethylformamide, dimethylsulfoxide, acetone, pyridine, chloroform and methanol were measured at 298.15 K. The solvation and hydrogen bonding enthalpies of ethers in the solvent are calculated. The influence of number of active centers in ethers on thermochemical parameters is shown. It was found that the formation of hydrogen bonds for linear and cyclic ethers with proton donors are different.
KW - Intermolecular interaction
KW - Linear and cyclic ethers
KW - Proton acceptors
KW - Proton donors
KW - Solution calorimetry
KW - Solution enthalpies
KW - CALORIMETRIC DETERMINATION
KW - BASE-ACID PROPERTIES
KW - BINARY-MIXTURES
KW - ORGANIC-SOLVENTS
KW - PROTON ACCEPTORS
KW - EXCESS-ENTHALPIES
KW - HEAT-CAPACITIES
KW - CROWN-ETHERS
KW - PLUS XH(2)O
KW - WATER
UR - http://www.scopus.com/inward/record.url?scp=85103686792&partnerID=8YFLogxK
UR - https://www.mendeley.com/catalogue/c7e45753-af1b-3670-a411-1cd6052b9f43/
U2 - 10.1016/j.tca.2021.178932
DO - 10.1016/j.tca.2021.178932
M3 - Article
AN - SCOPUS:85103686792
VL - 700
JO - Thermochimica Acta
JF - Thermochimica Acta
SN - 0040-6031
M1 - 178932
ER -
ID: 77055537