Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Thermochemistry of Solution, Solvation and Hydrogen Bonding of Chloroform in Linear and Cyclic Ethers. / Rakipov, Ilnaz T.; Semenov, Konstantin N.; Petrov, Artem A.; Akhmadiyarov, Aydar A.; Khachatrian, Artashes A.; Fakhurtdinova, Aliya R.; Solomonov, Boris N.
в: Journal of Solution Chemistry, Том 50, № 2, 01.02.2021, стр. 290-298.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
}
TY - JOUR
T1 - Thermochemistry of Solution, Solvation and Hydrogen Bonding of Chloroform in Linear and Cyclic Ethers
AU - Rakipov, Ilnaz T.
AU - Semenov, Konstantin N.
AU - Petrov, Artem A.
AU - Akhmadiyarov, Aydar A.
AU - Khachatrian, Artashes A.
AU - Fakhurtdinova, Aliya R.
AU - Solomonov, Boris N.
N1 - Publisher Copyright: © 2021, The Author(s), under exclusive licence to Springer Science+Business Media, LLC part of Springer Nature. Copyright: Copyright 2021 Elsevier B.V., All rights reserved.
PY - 2021/2/1
Y1 - 2021/2/1
N2 - In this work the thermochemistry of solution, solvation and hydrogen bond formation of chloroform in linear and cyclic ethers was studied. The infinite dilution solution enthalpies of chloroform in diethyl ether, diglyme, 1,4-dioxane, tetrahydrofuran, 12-crown-4 and 15-crown-5 were measured at 298.15 K. The solvation and hydrogen bonding enthalpies of chloroform in the ethers were calculated. It was found that the hydrogen bonding enthalpies of chloroform in the ethers are significantly higher for linear than for cyclic ethers. The hydrogen bonding of ethers with chloroform was discussed in cases when ethers act as a solute or solvent.
AB - In this work the thermochemistry of solution, solvation and hydrogen bond formation of chloroform in linear and cyclic ethers was studied. The infinite dilution solution enthalpies of chloroform in diethyl ether, diglyme, 1,4-dioxane, tetrahydrofuran, 12-crown-4 and 15-crown-5 were measured at 298.15 K. The solvation and hydrogen bonding enthalpies of chloroform in the ethers were calculated. It was found that the hydrogen bonding enthalpies of chloroform in the ethers are significantly higher for linear than for cyclic ethers. The hydrogen bonding of ethers with chloroform was discussed in cases when ethers act as a solute or solvent.
KW - Intermolecular interaction
KW - Linear and cyclic ethers
KW - Proton donors
KW - Solution calorimetry
KW - Solution enthalpies
UR - http://www.scopus.com/inward/record.url?scp=85101194486&partnerID=8YFLogxK
UR - https://www.mendeley.com/catalogue/e58bf814-7892-3938-a63c-996dbab61527/
U2 - 10.1007/s10953-021-01059-6
DO - 10.1007/s10953-021-01059-6
M3 - Article
AN - SCOPUS:85101194486
VL - 50
SP - 290
EP - 298
JO - Journal of Solution Chemistry
JF - Journal of Solution Chemistry
SN - 0095-9782
IS - 2
ER -
ID: 77056231