Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Thermal isomerization of 3,3-dihalo-1,2-diphenylaziridines. / Kostikov, R. R.; Khlebnikov, A. F.; Ogloblin, K. A.
в: Chemistry of Heterocyclic Compounds, Том 14, № 1, 01.01.1978, стр. 37-41.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
}
TY - JOUR
T1 - Thermal isomerization of 3,3-dihalo-1,2-diphenylaziridines
AU - Kostikov, R. R.
AU - Khlebnikov, A. F.
AU - Ogloblin, K. A.
PY - 1978/1/1
Y1 - 1978/1/1
N2 - The kinetics of thermal isomerization of 3,3-dihalo-1,2-diphenylaziridines containing fluorine, chlorine, or bromine atoms in the ring were studied, and the activation parameters of the reaction were determined. A concerted mechanism for the formation of imidoyl halides from haloaziridines that includes conrotatory opening of the aziridine ring with halogen migration of the 1,2 type is proposed on the basis of the data obtained.
AB - The kinetics of thermal isomerization of 3,3-dihalo-1,2-diphenylaziridines containing fluorine, chlorine, or bromine atoms in the ring were studied, and the activation parameters of the reaction were determined. A concerted mechanism for the formation of imidoyl halides from haloaziridines that includes conrotatory opening of the aziridine ring with halogen migration of the 1,2 type is proposed on the basis of the data obtained.
UR - http://www.scopus.com/inward/record.url?scp=34250278924&partnerID=8YFLogxK
U2 - 10.1007/BF00635939
DO - 10.1007/BF00635939
M3 - Article
AN - SCOPUS:34250278924
VL - 14
SP - 37
EP - 41
JO - Chemistry of Heterocyclic Compounds
JF - Chemistry of Heterocyclic Compounds
SN - 0009-3122
IS - 1
ER -
ID: 28245228