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Thermal Decomposition of Aluminium Hydride Complexes with Trimethylamine and N-Heterocyclic Carbene. / Doinikov, D. A. ; Zavgorodnii, A. S. ; Kazakov, I. V. ; Kravtcov, D. V. ; Chernysheva, A. M. ; Shcherbina, N. A. ; Timoshkin, A. Yu. .

в: Russian Journal of General Chemistry, Том 91, № 10, 10.2021, стр. 1969–1976.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

Harvard

Doinikov, DA, Zavgorodnii, AS, Kazakov, IV, Kravtcov, DV, Chernysheva, AM, Shcherbina, NA & Timoshkin, AY 2021, 'Thermal Decomposition of Aluminium Hydride Complexes with Trimethylamine and N-Heterocyclic Carbene', Russian Journal of General Chemistry, Том. 91, № 10, стр. 1969–1976. https://doi.org/10.1134/s1070363221100078

APA

Doinikov, D. A., Zavgorodnii, A. S., Kazakov, I. V., Kravtcov, D. V., Chernysheva, A. M., Shcherbina, N. A., & Timoshkin, A. Y. (2021). Thermal Decomposition of Aluminium Hydride Complexes with Trimethylamine and N-Heterocyclic Carbene. Russian Journal of General Chemistry, 91(10), 1969–1976. https://doi.org/10.1134/s1070363221100078

Vancouver

Doinikov DA, Zavgorodnii AS, Kazakov IV, Kravtcov DV, Chernysheva AM, Shcherbina NA и пр. Thermal Decomposition of Aluminium Hydride Complexes with Trimethylamine and N-Heterocyclic Carbene. Russian Journal of General Chemistry. 2021 Окт.;91(10):1969–1976. https://doi.org/10.1134/s1070363221100078

Author

Doinikov, D. A. ; Zavgorodnii, A. S. ; Kazakov, I. V. ; Kravtcov, D. V. ; Chernysheva, A. M. ; Shcherbina, N. A. ; Timoshkin, A. Yu. . / Thermal Decomposition of Aluminium Hydride Complexes with Trimethylamine and N-Heterocyclic Carbene. в: Russian Journal of General Chemistry. 2021 ; Том 91, № 10. стр. 1969–1976.

BibTeX

@article{65ee84661fb1401fb18f3eea584dbbe5,
title = "Thermal Decomposition of Aluminium Hydride Complexes with Trimethylamine and N-Heterocyclic Carbene",
abstract = "The decomposition of aluminum hydride complexes with trimethylamine and N-heterocyclic carbene—1,3-bis(2,6-diisopropylphenyl)-1,3-dihydro-2H-imidazol-2-ylidene was studied by a static tensimetric method with a membrane null-manometer. The AlH3·NMe3 complex passes into vapor in the form of monomeric molecules and in unsaturated vapor slowly decomposes at 70‒80°С into solid aluminum, gaseous trimethylamine, and hydrogen. The decomposition is accompanied by an induction period, the duration of which decreases as temperature increases. The AlH3 complex with carbene slowly decomposes at 170‒200°С with a rate practically independent of temperature.",
keywords = "molecular complexes, aluminum hydride, trimethylamine, N-heterocyclic carbene, tensimetry, thermal decomposition, molecular complexes, aluminum hydride, trimethylamine, N-heterocyclic carbene, tensimetry, thermal decomposition, THIN-FILMS, CHEMICAL-VAPOR-DEPOSITION, CRYSTAL-STRUCTURE, COORDINATION, HYDROGEN, KINETICS, AL-H, CHEMISTRY, ALANE, PHASE-CHANGE",
author = "Doinikov, {D. A.} and Zavgorodnii, {A. S.} and Kazakov, {I. V.} and Kravtcov, {D. V.} and Chernysheva, {A. M.} and Shcherbina, {N. A.} and Timoshkin, {A. Yu.}",
note = "Publisher Copyright: {\textcopyright} 2021, Pleiades Publishing, Ltd.",
year = "2021",
month = oct,
doi = "10.1134/s1070363221100078",
language = "English",
volume = "91",
pages = "1969–1976",
journal = "Russian Journal of General Chemistry",
issn = "1070-3632",
publisher = "МАИК {"}Наука/Интерпериодика{"}",
number = "10",

}

RIS

TY - JOUR

T1 - Thermal Decomposition of Aluminium Hydride Complexes with Trimethylamine and N-Heterocyclic Carbene

AU - Doinikov, D. A.

AU - Zavgorodnii, A. S.

AU - Kazakov, I. V.

AU - Kravtcov, D. V.

AU - Chernysheva, A. M.

AU - Shcherbina, N. A.

AU - Timoshkin, A. Yu.

N1 - Publisher Copyright: © 2021, Pleiades Publishing, Ltd.

PY - 2021/10

Y1 - 2021/10

N2 - The decomposition of aluminum hydride complexes with trimethylamine and N-heterocyclic carbene—1,3-bis(2,6-diisopropylphenyl)-1,3-dihydro-2H-imidazol-2-ylidene was studied by a static tensimetric method with a membrane null-manometer. The AlH3·NMe3 complex passes into vapor in the form of monomeric molecules and in unsaturated vapor slowly decomposes at 70‒80°С into solid aluminum, gaseous trimethylamine, and hydrogen. The decomposition is accompanied by an induction period, the duration of which decreases as temperature increases. The AlH3 complex with carbene slowly decomposes at 170‒200°С with a rate practically independent of temperature.

AB - The decomposition of aluminum hydride complexes with trimethylamine and N-heterocyclic carbene—1,3-bis(2,6-diisopropylphenyl)-1,3-dihydro-2H-imidazol-2-ylidene was studied by a static tensimetric method with a membrane null-manometer. The AlH3·NMe3 complex passes into vapor in the form of monomeric molecules and in unsaturated vapor slowly decomposes at 70‒80°С into solid aluminum, gaseous trimethylamine, and hydrogen. The decomposition is accompanied by an induction period, the duration of which decreases as temperature increases. The AlH3 complex with carbene slowly decomposes at 170‒200°С with a rate practically independent of temperature.

KW - molecular complexes

KW - aluminum hydride

KW - trimethylamine

KW - N-heterocyclic carbene

KW - tensimetry

KW - thermal decomposition

KW - molecular complexes

KW - aluminum hydride

KW - trimethylamine

KW - N-heterocyclic carbene

KW - tensimetry

KW - thermal decomposition

KW - THIN-FILMS

KW - CHEMICAL-VAPOR-DEPOSITION

KW - CRYSTAL-STRUCTURE

KW - COORDINATION

KW - HYDROGEN

KW - KINETICS

KW - AL-H

KW - CHEMISTRY

KW - ALANE

KW - PHASE-CHANGE

UR - https://link.springer.com/article/10.1134/S1070363221100078

UR - http://www.scopus.com/inward/record.url?scp=85118761603&partnerID=8YFLogxK

UR - https://www.mendeley.com/catalogue/27f36ad2-b271-3fe3-be5f-8a799311df13/

U2 - 10.1134/s1070363221100078

DO - 10.1134/s1070363221100078

M3 - Article

VL - 91

SP - 1969

EP - 1976

JO - Russian Journal of General Chemistry

JF - Russian Journal of General Chemistry

SN - 1070-3632

IS - 10

ER -

ID: 87892547