TY - JOUR

T1 - Theoretical Studies of Cycloaddition to Metal-Activated Substrates with Isocyanide Ligands

AU - Novikov, A. S.

N1 - Funding Information: ACKNOWLEDGMENTS This work was supported by the Russian Science Foundation, project 14-43-00017P.

PY - 2018/4/1

Y1 - 2018/4/1

N2 - The results of theoretical studies of the reactions of cycloaddition to the metal-activated substrates with the isocyamide ligands performed by the author and coworkers within the recent five years are generalized and examined. The reaction mechanisms, main factors, and driving forces affecting the kinetic and thermodynamic parameters of the processes are considered.

AB - The results of theoretical studies of the reactions of cycloaddition to the metal-activated substrates with the isocyamide ligands performed by the author and coworkers within the recent five years are generalized and examined. The reaction mechanisms, main factors, and driving forces affecting the kinetic and thermodynamic parameters of the processes are considered.

KW - cycloaddition

KW - isocyanides

KW - mechanisms of reactions

KW - quantum-chemical calculations

KW - reactivity

KW - BORON

KW - DFT

KW - NITRONES

KW - NEUTRON-CAPTURE THERAPY

KW - REACTIVITY

KW - RH(III) BIS(ISONITRILE) COMPLEXES

KW - CANCER

UR - http://www.scopus.com/inward/record.url?scp=85045390066&partnerID=8YFLogxK

U2 - 10.1134/S1070328418040073

DO - 10.1134/S1070328418040073

M3 - Article

VL - 44

SP - 252

EP - 257

JO - Russian Journal of Coordination Chemistry

JF - Russian Journal of Coordination Chemistry

SN - 1070-3284

IS - 4

ER -