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The T-shaped NeI2 (E0g +) van der Waals complex. / Baturo, V. V.; Lukashov, S. S.; Poretsky, S. A.; Pravilov, A. M.

в: Journal of Physics B: Atomic, Molecular and Optical Physics, Том 52, № 14, 145101, 28.07.2019.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

Harvard

Baturo, VV, Lukashov, SS, Poretsky, SA & Pravilov, AM 2019, 'The T-shaped NeI2 (E0g +) van der Waals complex', Journal of Physics B: Atomic, Molecular and Optical Physics, Том. 52, № 14, 145101. https://doi.org/10.1088/1361-6455/ab2496

APA

Baturo, V. V., Lukashov, S. S., Poretsky, S. A., & Pravilov, A. M. (2019). The T-shaped NeI2 (E0g +) van der Waals complex. Journal of Physics B: Atomic, Molecular and Optical Physics, 52(14), [145101]. https://doi.org/10.1088/1361-6455/ab2496

Vancouver

Baturo VV, Lukashov SS, Poretsky SA, Pravilov AM. The T-shaped NeI2 (E0g +) van der Waals complex. Journal of Physics B: Atomic, Molecular and Optical Physics. 2019 Июль 28;52(14). 145101. https://doi.org/10.1088/1361-6455/ab2496

Author

Baturo, V. V. ; Lukashov, S. S. ; Poretsky, S. A. ; Pravilov, A. M. / The T-shaped NeI2 (E0g +) van der Waals complex. в: Journal of Physics B: Atomic, Molecular and Optical Physics. 2019 ; Том 52, № 14.

BibTeX

@article{a92ffe86665348bb98b1ed29b6be92be,
title = "The T-shaped NeI2 (E0g +) van der Waals complex",
abstract = "The vibrational and electronic predissociation of the NeI2(E ) complexes has been studied for the first time using two-step laser excitation of the complexes formed in a supersonic molecular beam. The I2(E → D → X β1g → A1u, γ1u → a1g and δ2u → 2g(aa)) luminescence have been observed, and luminescence spectra of these transitions have been measured. We have determined binding energies of the NeI2(E, v E = 0-6, n E) complexes, vibrational populations of the E, D, and β states as well as branching ratios of the vibrational and electronic predissociation channels. It has been shown that binding energies of the RgI2(E, v E = 0, n E = 0) vdW complexes, Rg = He-Kr, are directly proportional to the Rg polarizabilities. PESs for NeI2(B, E) complexes have been constructed in a diatomics-in-molecule model. These surfaces describe adequately excitation spectra of the luminescence observed. The NeI2(E, v E, n E) complex electronic predissociation is described in the framework of the energy gap model.",
keywords = "binding energy, dynamics, iodine molecule, ion-pair states, neon, structure, van der Waals complexes, MOLECULAR-IODINE, DOUBLE-RESONANCE SPECTROSCOPY, GROUND-STATE, I-2, ION-PAIR STATES, NOBLE GAS-HALOGEN, AR, NONADIABATIC TRANSITIONS, CLUSTERS, REAL-TIME DYNAMICS",
author = "Baturo, {V. V.} and Lukashov, {S. S.} and Poretsky, {S. A.} and Pravilov, {A. M.}",
year = "2019",
month = jul,
day = "28",
doi = "10.1088/1361-6455/ab2496",
language = "English",
volume = "52",
journal = "Journal of the European Optical Society Part B: Quantum Optics",
issn = "0953-4075",
publisher = "IOP Publishing Ltd.",
number = "14",

}

RIS

TY - JOUR

T1 - The T-shaped NeI2 (E0g +) van der Waals complex

AU - Baturo, V. V.

AU - Lukashov, S. S.

AU - Poretsky, S. A.

AU - Pravilov, A. M.

PY - 2019/7/28

Y1 - 2019/7/28

N2 - The vibrational and electronic predissociation of the NeI2(E ) complexes has been studied for the first time using two-step laser excitation of the complexes formed in a supersonic molecular beam. The I2(E → D → X β1g → A1u, γ1u → a1g and δ2u → 2g(aa)) luminescence have been observed, and luminescence spectra of these transitions have been measured. We have determined binding energies of the NeI2(E, v E = 0-6, n E) complexes, vibrational populations of the E, D, and β states as well as branching ratios of the vibrational and electronic predissociation channels. It has been shown that binding energies of the RgI2(E, v E = 0, n E = 0) vdW complexes, Rg = He-Kr, are directly proportional to the Rg polarizabilities. PESs for NeI2(B, E) complexes have been constructed in a diatomics-in-molecule model. These surfaces describe adequately excitation spectra of the luminescence observed. The NeI2(E, v E, n E) complex electronic predissociation is described in the framework of the energy gap model.

AB - The vibrational and electronic predissociation of the NeI2(E ) complexes has been studied for the first time using two-step laser excitation of the complexes formed in a supersonic molecular beam. The I2(E → D → X β1g → A1u, γ1u → a1g and δ2u → 2g(aa)) luminescence have been observed, and luminescence spectra of these transitions have been measured. We have determined binding energies of the NeI2(E, v E = 0-6, n E) complexes, vibrational populations of the E, D, and β states as well as branching ratios of the vibrational and electronic predissociation channels. It has been shown that binding energies of the RgI2(E, v E = 0, n E = 0) vdW complexes, Rg = He-Kr, are directly proportional to the Rg polarizabilities. PESs for NeI2(B, E) complexes have been constructed in a diatomics-in-molecule model. These surfaces describe adequately excitation spectra of the luminescence observed. The NeI2(E, v E, n E) complex electronic predissociation is described in the framework of the energy gap model.

KW - binding energy

KW - dynamics

KW - iodine molecule

KW - ion-pair states

KW - neon

KW - structure

KW - van der Waals complexes

KW - MOLECULAR-IODINE

KW - DOUBLE-RESONANCE SPECTROSCOPY

KW - GROUND-STATE

KW - I-2

KW - ION-PAIR STATES

KW - NOBLE GAS-HALOGEN

KW - AR

KW - NONADIABATIC TRANSITIONS

KW - CLUSTERS

KW - REAL-TIME DYNAMICS

UR - http://www.scopus.com/inward/record.url?scp=85068992372&partnerID=8YFLogxK

U2 - 10.1088/1361-6455/ab2496

DO - 10.1088/1361-6455/ab2496

M3 - Article

AN - SCOPUS:85068992372

VL - 52

JO - Journal of the European Optical Society Part B: Quantum Optics

JF - Journal of the European Optical Society Part B: Quantum Optics

SN - 0953-4075

IS - 14

M1 - 145101

ER -

ID: 46069220