Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
The trans-Alkynylphosphine Oxide Complex of Pt(II): Synthesis, Spectroscopic Characterization, Crystal and Electronic Structures. / Snetkov, D.A.; Malazoniya, M.A.; Slavova, S.O.; Luginin, M.E.; Grachova, E.V.
в: Journal of Structural Chemistry, Том 67, № 1, 01.01.2026, стр. 164-174.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - The trans-Alkynylphosphine Oxide Complex of Pt(II): Synthesis, Spectroscopic Characterization, Crystal and Electronic Structures
AU - Snetkov, D.A.
AU - Malazoniya, M.A.
AU - Slavova, S.O.
AU - Luginin, M.E.
AU - Grachova, E.V.
N1 - Export Date: 09 March 2026; Cited By: 0; Correspondence Address: E.V. Grachova; Institute of Chemistry, St. Petersburg State University, St. Petersburg, Russian Federation; email: e.grachova@spbu.ru; CODEN: JSTCA
PY - 2026/1/1
Y1 - 2026/1/1
N2 - Abstract: A new trans-bisalkynyl complex of Pt(II) is synthesized. It contains alkynyl ligands with the diphenylphosphoryl group and additional triphenylphosphine ligands. The composition and structure of the obtained complex are determined by high-resolution mass spectroscopy, polynuclear NMR and IR spectroscopy techniques. The molecular structure of the complex is determined by the single crystal X-ray diffraction analysis. The obtained complex is not found to demonstrate photoluminescence, which can be explained by the atypical composition and energy of electronic transitions described based on the quantum chemical computations. © Pleiades Publishing, Ltd. 2026.
AB - Abstract: A new trans-bisalkynyl complex of Pt(II) is synthesized. It contains alkynyl ligands with the diphenylphosphoryl group and additional triphenylphosphine ligands. The composition and structure of the obtained complex are determined by high-resolution mass spectroscopy, polynuclear NMR and IR spectroscopy techniques. The molecular structure of the complex is determined by the single crystal X-ray diffraction analysis. The obtained complex is not found to demonstrate photoluminescence, which can be explained by the atypical composition and energy of electronic transitions described based on the quantum chemical computations. © Pleiades Publishing, Ltd. 2026.
KW - alkynyl complexes
KW - alkynylphosphine oxide
KW - platinum(II)
KW - quantum chemical computations
KW - structure
UR - https://www.mendeley.com/catalogue/664c05cd-fef5-3505-afb6-4d7f8f1bdf6f/
U2 - 10.1134/s0022476626010178
DO - 10.1134/s0022476626010178
M3 - статья
VL - 67
SP - 164
EP - 174
JO - Journal of Structural Chemistry
JF - Journal of Structural Chemistry
SN - 0022-4766
IS - 1
ER -
ID: 150126471