Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
The study of Bi3B5O12 : Synthesis, crystal structure and thermal expansion of oxoborate Bi3B5O 12. / Filatov, Stanislav; Shepelev, Yurij; Bubnova, Rimma; Sennova, Natalia; Egorysheva, Anna V.; Kargin, Yury F.
в: Journal of Solid State Chemistry, Том 177, № 2, 02.2004, стр. 515-522.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - The study of Bi3B5O12
T2 - Synthesis, crystal structure and thermal expansion of oxoborate Bi3B5O 12
AU - Filatov, Stanislav
AU - Shepelev, Yurij
AU - Bubnova, Rimma
AU - Sennova, Natalia
AU - Egorysheva, Anna V.
AU - Kargin, Yury F.
PY - 2004/2
Y1 - 2004/2
N2 - The paper presents a new data on the crystal structure, thermal expansion and IR spectra of Bi3B5O12. The Bi 3B5O12 single crystals were grown from the melt of the same stoichiometry by Czochralski technique. The crystal structure of Bi3B5O12 was refined in anisotropic approximation using single-crystal X-ray diffraction data. It is orthorhombic, Pnma, a=6.530(4), b=7.726(5), c=18.578(5)Å, V=937.2(5)Å 3, Z=4, R=3.45%. Bi3+ atoms have irregular coordination polyhedra, Bi(1)O6 (d(B-O)=2.09-2.75Å) and Bi(2)O7 (d(B-O)=2.108-2.804Å). Taking into account the shortest bonds only, these polyhedra are considered here as trigonal Bi(1)O3 (2.09-2.20Å) and tetragonal Bi(2)O4 (2.108-2.331Å) irregular pyramids with Bi atoms in the tops of both pyramids. The BiO4 polyhedra form zigzag chains along b-axis. These chains alternate with isolated anions [B 2IVB3IIIO11] 7- through the common oxygen atoms to form thick layers extended in ab plane. A perfect cleavage of the compound corresponds to these layers and an imperfect one is parallel to the Bi-O chains. The Bi3B 5O12 thermal expansion is sharply anisotropic (α11≈α22=12, α33= 3×10-6°C-1) likely due to a straightening of the flexible zigzag chains along b-axis and decreasing of their zigzag along c-axis. Thus the properties like cleavage and thermal expansion correlate to these chains.
AB - The paper presents a new data on the crystal structure, thermal expansion and IR spectra of Bi3B5O12. The Bi 3B5O12 single crystals were grown from the melt of the same stoichiometry by Czochralski technique. The crystal structure of Bi3B5O12 was refined in anisotropic approximation using single-crystal X-ray diffraction data. It is orthorhombic, Pnma, a=6.530(4), b=7.726(5), c=18.578(5)Å, V=937.2(5)Å 3, Z=4, R=3.45%. Bi3+ atoms have irregular coordination polyhedra, Bi(1)O6 (d(B-O)=2.09-2.75Å) and Bi(2)O7 (d(B-O)=2.108-2.804Å). Taking into account the shortest bonds only, these polyhedra are considered here as trigonal Bi(1)O3 (2.09-2.20Å) and tetragonal Bi(2)O4 (2.108-2.331Å) irregular pyramids with Bi atoms in the tops of both pyramids. The BiO4 polyhedra form zigzag chains along b-axis. These chains alternate with isolated anions [B 2IVB3IIIO11] 7- through the common oxygen atoms to form thick layers extended in ab plane. A perfect cleavage of the compound corresponds to these layers and an imperfect one is parallel to the Bi-O chains. The Bi3B 5O12 thermal expansion is sharply anisotropic (α11≈α22=12, α33= 3×10-6°C-1) likely due to a straightening of the flexible zigzag chains along b-axis and decreasing of their zigzag along c-axis. Thus the properties like cleavage and thermal expansion correlate to these chains.
KW - BiBO
KW - Bismuth borate
KW - Crystal structure
KW - IR spectroscopy
KW - Isolated boron-oxygen anion
KW - Oxoborate
KW - Oxocentered polyhedra
KW - Thermal expansion
UR - http://www.scopus.com/inward/record.url?scp=0442295084&partnerID=8YFLogxK
U2 - 10.1016/j.jssc.2003.03.003
DO - 10.1016/j.jssc.2003.03.003
M3 - Article
AN - SCOPUS:0442295084
VL - 177
SP - 515
EP - 522
JO - Journal of Solid State Chemistry
JF - Journal of Solid State Chemistry
SN - 0022-4596
IS - 2
ER -
ID: 53951881