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The stabilisation of monomeric parent compounds of phosphanyl- and arsanylboranes. / Vogel, Ulf; Hoemensch, Petra; Schwan, Karl Christian; Timoshkin, Alexey Y.; Scheer, Manfred.

в: Chemistry - A European Journal, Том 9, № 2, 20.01.2003, стр. 515-519.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

Harvard

Vogel, U, Hoemensch, P, Schwan, KC, Timoshkin, AY & Scheer, M 2003, 'The stabilisation of monomeric parent compounds of phosphanyl- and arsanylboranes', Chemistry - A European Journal, Том. 9, № 2, стр. 515-519. https://doi.org/10.1002/chem.200390054

APA

Vogel, U., Hoemensch, P., Schwan, K. C., Timoshkin, A. Y., & Scheer, M. (2003). The stabilisation of monomeric parent compounds of phosphanyl- and arsanylboranes. Chemistry - A European Journal, 9(2), 515-519. https://doi.org/10.1002/chem.200390054

Vancouver

Vogel U, Hoemensch P, Schwan KC, Timoshkin AY, Scheer M. The stabilisation of monomeric parent compounds of phosphanyl- and arsanylboranes. Chemistry - A European Journal. 2003 Янв. 20;9(2):515-519. https://doi.org/10.1002/chem.200390054

Author

Vogel, Ulf ; Hoemensch, Petra ; Schwan, Karl Christian ; Timoshkin, Alexey Y. ; Scheer, Manfred. / The stabilisation of monomeric parent compounds of phosphanyl- and arsanylboranes. в: Chemistry - A European Journal. 2003 ; Том 9, № 2. стр. 515-519.

BibTeX

@article{ca7ef3ebe5de40df843500a74ebb5d69,
title = "The stabilisation of monomeric parent compounds of phosphanyl- and arsanylboranes",
abstract = "The structures of the parent compounds of phosphanyl- and arsanylboranes, H2BPH2 and H2BAsH2, were calculated by DFT-B3LYP methods. Such compounds have not previously been obtained preparatively. By applying the concept of Lewis acid/base stabilisation, [(CO)5W(H2EBH2·NMe3)] (E=P (3), As (4)) derivatives have been synthesised by the metathesis reactions between Li[(CO)5WEH2] and ClH2BNMe3 (E=P, As). Comprehensive thermodynamic studies on these systems verify the high stability of the Lewis acid/base stabilised complexes. Unexpected based on the thermodynamic calculations, UV radiation of the phosphanylborane 3 leads to the dinuclear phosphanido-bridged complex [(CO)8W2(μ-PHBH2· NMe3)2] (5) by H2 and CO elimination.",
keywords = "Arsenic, Boron, Density functional calculations, Phosphorus, Tungsten",
author = "Ulf Vogel and Petra Hoemensch and Schwan, {Karl Christian} and Timoshkin, {Alexey Y.} and Manfred Scheer",
year = "2003",
month = jan,
day = "20",
doi = "10.1002/chem.200390054",
language = "English",
volume = "9",
pages = "515--519",
journal = "Chemistry - A European Journal",
issn = "0947-6539",
publisher = "Wiley-Blackwell",
number = "2",

}

RIS

TY - JOUR

T1 - The stabilisation of monomeric parent compounds of phosphanyl- and arsanylboranes

AU - Vogel, Ulf

AU - Hoemensch, Petra

AU - Schwan, Karl Christian

AU - Timoshkin, Alexey Y.

AU - Scheer, Manfred

PY - 2003/1/20

Y1 - 2003/1/20

N2 - The structures of the parent compounds of phosphanyl- and arsanylboranes, H2BPH2 and H2BAsH2, were calculated by DFT-B3LYP methods. Such compounds have not previously been obtained preparatively. By applying the concept of Lewis acid/base stabilisation, [(CO)5W(H2EBH2·NMe3)] (E=P (3), As (4)) derivatives have been synthesised by the metathesis reactions between Li[(CO)5WEH2] and ClH2BNMe3 (E=P, As). Comprehensive thermodynamic studies on these systems verify the high stability of the Lewis acid/base stabilised complexes. Unexpected based on the thermodynamic calculations, UV radiation of the phosphanylborane 3 leads to the dinuclear phosphanido-bridged complex [(CO)8W2(μ-PHBH2· NMe3)2] (5) by H2 and CO elimination.

AB - The structures of the parent compounds of phosphanyl- and arsanylboranes, H2BPH2 and H2BAsH2, were calculated by DFT-B3LYP methods. Such compounds have not previously been obtained preparatively. By applying the concept of Lewis acid/base stabilisation, [(CO)5W(H2EBH2·NMe3)] (E=P (3), As (4)) derivatives have been synthesised by the metathesis reactions between Li[(CO)5WEH2] and ClH2BNMe3 (E=P, As). Comprehensive thermodynamic studies on these systems verify the high stability of the Lewis acid/base stabilised complexes. Unexpected based on the thermodynamic calculations, UV radiation of the phosphanylborane 3 leads to the dinuclear phosphanido-bridged complex [(CO)8W2(μ-PHBH2· NMe3)2] (5) by H2 and CO elimination.

KW - Arsenic

KW - Boron

KW - Density functional calculations

KW - Phosphorus

KW - Tungsten

UR - http://www.scopus.com/inward/record.url?scp=0037455222&partnerID=8YFLogxK

U2 - 10.1002/chem.200390054

DO - 10.1002/chem.200390054

M3 - Article

AN - SCOPUS:0037455222

VL - 9

SP - 515

EP - 519

JO - Chemistry - A European Journal

JF - Chemistry - A European Journal

SN - 0947-6539

IS - 2

ER -

ID: 17373687