Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
The possibilities and limitations of electrostatic approximation in determining the orientation of OH-bonds in layered silicates. / Bukin, A. S.; Drits, V. A.; Rozhdestvenskaya, I. V.; Semenova, T. F.; Tsipursky, S. I.
в: Mineralogicheskii Zhurnal, Том 4, № 3, 01.01.1982, стр. 29-34.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - The possibilities and limitations of electrostatic approximation in determining the orientation of OH-bonds in layered silicates.
AU - Bukin, A. S.
AU - Drits, V. A.
AU - Rozhdestvenskaya, I. V.
AU - Semenova, T. F.
AU - Tsipursky, S. I.
PY - 1982/1/1
Y1 - 1982/1/1
N2 - Orientations of the OH-vectors of the structural OH-groups of layered silicates have been determined from diffraction data and from calculations of electrostatic energy. A comparison of the results from both methods has shown that in the hydroxyls of the 2:1 layers of micas and chlorites, the position of the hydroxyl proton is mainly determined by electrostatics. In the case of the internal hydroxyls of dickite and those of the brucite lattice of the chlorites, the results derived from these two methods differ constantly, indicating a change in the nature of the bond in these hydroxyl groups. -D.A.B.
AB - Orientations of the OH-vectors of the structural OH-groups of layered silicates have been determined from diffraction data and from calculations of electrostatic energy. A comparison of the results from both methods has shown that in the hydroxyls of the 2:1 layers of micas and chlorites, the position of the hydroxyl proton is mainly determined by electrostatics. In the case of the internal hydroxyls of dickite and those of the brucite lattice of the chlorites, the results derived from these two methods differ constantly, indicating a change in the nature of the bond in these hydroxyl groups. -D.A.B.
UR - http://www.scopus.com/inward/record.url?scp=0019912005&partnerID=8YFLogxK
M3 - статья
AN - SCOPUS:0019912005
VL - 4
SP - 29
EP - 34
JO - МИНЕРАЛОГИЧЕСКИЙ ЖУРНАЛ
JF - МИНЕРАЛОГИЧЕСКИЙ ЖУРНАЛ
SN - 0204-3548
IS - 3
ER -
ID: 50027533