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The hybridized M3d-F2p character of low-energy unoccupied electron states in 3d metal fluorides observed by F 1s absorption. / Vinogradov, A. S.; Fedoseenko, S. I.; Krasnikov, S. A.; Preobrajenski, A. B.; Sivkov, V. N.; Vyalikh, D. V.; Molodtsov, S. L.; Adamchuk, V. K.; Laubschat, C.; Kaindl, G.

в: Physica Scripta T, Том T115, 01.12.2005, стр. 510-512.

Результаты исследований: Научные публикации в периодических изданияхстатьяРецензирование

Harvard

Vinogradov, AS, Fedoseenko, SI, Krasnikov, SA, Preobrajenski, AB, Sivkov, VN, Vyalikh, DV, Molodtsov, SL, Adamchuk, VK, Laubschat, C & Kaindl, G 2005, 'The hybridized M3d-F2p character of low-energy unoccupied electron states in 3d metal fluorides observed by F 1s absorption', Physica Scripta T, Том. T115, стр. 510-512. https://doi.org/10.1238/Physica.Topical.115a00510

APA

Vinogradov, A. S., Fedoseenko, S. I., Krasnikov, S. A., Preobrajenski, A. B., Sivkov, V. N., Vyalikh, D. V., Molodtsov, S. L., Adamchuk, V. K., Laubschat, C., & Kaindl, G. (2005). The hybridized M3d-F2p character of low-energy unoccupied electron states in 3d metal fluorides observed by F 1s absorption. Physica Scripta T, T115, 510-512. https://doi.org/10.1238/Physica.Topical.115a00510

Vancouver

Author

Vinogradov, A. S. ; Fedoseenko, S. I. ; Krasnikov, S. A. ; Preobrajenski, A. B. ; Sivkov, V. N. ; Vyalikh, D. V. ; Molodtsov, S. L. ; Adamchuk, V. K. ; Laubschat, C. ; Kaindl, G. / The hybridized M3d-F2p character of low-energy unoccupied electron states in 3d metal fluorides observed by F 1s absorption. в: Physica Scripta T. 2005 ; Том T115. стр. 510-512.

BibTeX

@article{65c27cf247e441a5beaee26b923e5609,
title = "The hybridized M3d-F2p character of low-energy unoccupied electron states in 3d metal fluorides observed by F 1s absorption",
abstract = "The near-edge fine structure of the F 1s absorption spectra of 3d metal fluorides was studied for the first time with high energy resolution. The spectra of these, the most ionic compounds of the 3d atoms, are analyzed comparing with the F 1s absorption spectrum of the molecular TiF 62- anion in solid K2TiF6. The latter spectrum was afore interpreted considering the fluorine spectra of the molecular PF6- anion in a KPF6 crystal and of the gas-phase SF6 molecule. The low-energy empty electron states in the 3d metal fluorides are shown to be formed due to covalent mixing of the metal 3d and fluorine 2p electron states. {\textcopyright} Physica Scripta 2005.",
author = "Vinogradov, {A. S.} and Fedoseenko, {S. I.} and Krasnikov, {S. A.} and Preobrajenski, {A. B.} and Sivkov, {V. N.} and Vyalikh, {D. V.} and Molodtsov, {S. L.} and Adamchuk, {V. K.} and C. Laubschat and G. Kaindl",
year = "2005",
month = dec,
day = "1",
doi = "10.1238/Physica.Topical.115a00510",
language = "English",
volume = "T115",
pages = "510--512",
journal = "Physica Scripta",
issn = "0031-8949",
publisher = "IOP Publishing Ltd.",

}

RIS

TY - JOUR

T1 - The hybridized M3d-F2p character of low-energy unoccupied electron states in 3d metal fluorides observed by F 1s absorption

AU - Vinogradov, A. S.

AU - Fedoseenko, S. I.

AU - Krasnikov, S. A.

AU - Preobrajenski, A. B.

AU - Sivkov, V. N.

AU - Vyalikh, D. V.

AU - Molodtsov, S. L.

AU - Adamchuk, V. K.

AU - Laubschat, C.

AU - Kaindl, G.

PY - 2005/12/1

Y1 - 2005/12/1

N2 - The near-edge fine structure of the F 1s absorption spectra of 3d metal fluorides was studied for the first time with high energy resolution. The spectra of these, the most ionic compounds of the 3d atoms, are analyzed comparing with the F 1s absorption spectrum of the molecular TiF 62- anion in solid K2TiF6. The latter spectrum was afore interpreted considering the fluorine spectra of the molecular PF6- anion in a KPF6 crystal and of the gas-phase SF6 molecule. The low-energy empty electron states in the 3d metal fluorides are shown to be formed due to covalent mixing of the metal 3d and fluorine 2p electron states. © Physica Scripta 2005.

AB - The near-edge fine structure of the F 1s absorption spectra of 3d metal fluorides was studied for the first time with high energy resolution. The spectra of these, the most ionic compounds of the 3d atoms, are analyzed comparing with the F 1s absorption spectrum of the molecular TiF 62- anion in solid K2TiF6. The latter spectrum was afore interpreted considering the fluorine spectra of the molecular PF6- anion in a KPF6 crystal and of the gas-phase SF6 molecule. The low-energy empty electron states in the 3d metal fluorides are shown to be formed due to covalent mixing of the metal 3d and fluorine 2p electron states. © Physica Scripta 2005.

UR - http://www.scopus.com/inward/record.url?scp=33749346739&partnerID=8YFLogxK

U2 - 10.1238/Physica.Topical.115a00510

DO - 10.1238/Physica.Topical.115a00510

M3 - Article

AN - SCOPUS:33749346739

VL - T115

SP - 510

EP - 512

JO - Physica Scripta

JF - Physica Scripta

SN - 0031-8949

ER -

ID: 127648612