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The effect of the protonic component of conduction on the electrical properties of oxide glass. / Pronkin, A. A.; Murin, I. V.; Sokolov, I. A.

в: Glass Physics and Chemistry, Том 41, № 1, 2015, стр. 54-58.

Результаты исследований: Научные публикации в периодических изданияхстатьяРецензирование

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Pronkin, A. A. ; Murin, I. V. ; Sokolov, I. A. / The effect of the protonic component of conduction on the electrical properties of oxide glass. в: Glass Physics and Chemistry. 2015 ; Том 41, № 1. стр. 54-58.

BibTeX

@article{364b547c39ff41c395b2df98c5721ad7,
title = "The effect of the protonic component of conduction on the electrical properties of oxide glass",
abstract = "A short review of works devoted to studying the effect of hydrogen-containing fragments of the structure (mainly H2O and OH−-groups) on the physicochemical (mainly electrical) properties of oxide glass has been presented. It was noted that the conduction of alkali-free oxide glass is due to the migration of protons. When introducing alkali metal oxides in their composition in the region of low Me2O concentrations, the electric current transport is due to the combined migration of protons and alkali metal ions; the conduction due to the migration of exclusively alkali ions is observed at concentrations of alkali metal ion oxides higher than 20 mol %. It was noted that in oxide glass containing ions of alkaline earth metals the conduction is also due to the migration of impurity protons. No participation of ions of alkaline earth metals in the electricity transport was observed.",
keywords = "concentration dependence of the electric conduction, ionic conduction, mixed protonic-ionic conduction, nature of the conduction of glass, oxide glass, protonic conduction",
author = "Pronkin, {A. A.} and Murin, {I. V.} and Sokolov, {I. A.}",
note = "Publisher Copyright: {\textcopyright} 2015, Pleiades Publishing, Ltd.",
year = "2015",
doi = "10.1134/S108765961501023X",
language = "English",
volume = "41",
pages = "54--58",
journal = "Glass Physics and Chemistry",
issn = "1087-6596",
publisher = "МАИК {"}Наука/Интерпериодика{"}",
number = "1",

}

RIS

TY - JOUR

T1 - The effect of the protonic component of conduction on the electrical properties of oxide glass

AU - Pronkin, A. A.

AU - Murin, I. V.

AU - Sokolov, I. A.

N1 - Publisher Copyright: © 2015, Pleiades Publishing, Ltd.

PY - 2015

Y1 - 2015

N2 - A short review of works devoted to studying the effect of hydrogen-containing fragments of the structure (mainly H2O and OH−-groups) on the physicochemical (mainly electrical) properties of oxide glass has been presented. It was noted that the conduction of alkali-free oxide glass is due to the migration of protons. When introducing alkali metal oxides in their composition in the region of low Me2O concentrations, the electric current transport is due to the combined migration of protons and alkali metal ions; the conduction due to the migration of exclusively alkali ions is observed at concentrations of alkali metal ion oxides higher than 20 mol %. It was noted that in oxide glass containing ions of alkaline earth metals the conduction is also due to the migration of impurity protons. No participation of ions of alkaline earth metals in the electricity transport was observed.

AB - A short review of works devoted to studying the effect of hydrogen-containing fragments of the structure (mainly H2O and OH−-groups) on the physicochemical (mainly electrical) properties of oxide glass has been presented. It was noted that the conduction of alkali-free oxide glass is due to the migration of protons. When introducing alkali metal oxides in their composition in the region of low Me2O concentrations, the electric current transport is due to the combined migration of protons and alkali metal ions; the conduction due to the migration of exclusively alkali ions is observed at concentrations of alkali metal ion oxides higher than 20 mol %. It was noted that in oxide glass containing ions of alkaline earth metals the conduction is also due to the migration of impurity protons. No participation of ions of alkaline earth metals in the electricity transport was observed.

KW - concentration dependence of the electric conduction

KW - ionic conduction

KW - mixed protonic-ionic conduction

KW - nature of the conduction of glass

KW - oxide glass

KW - protonic conduction

UR - http://www.scopus.com/inward/record.url?scp=84922813439&partnerID=8YFLogxK

U2 - 10.1134/S108765961501023X

DO - 10.1134/S108765961501023X

M3 - Article

VL - 41

SP - 54

EP - 58

JO - Glass Physics and Chemistry

JF - Glass Physics and Chemistry

SN - 1087-6596

IS - 1

ER -

ID: 3936291