The effect of reaction medium and hydrothermal synthesis conditions on morphological parameters and thermal behavior of calcium phosphate nanoparticles

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The effect of reaction medium and hydrothermal synthesis conditions on morphological parameters and thermal behavior of calcium phosphate nanoparticles. / Syukkalova, Evgeniya A.; Sadetskaya, Anastasia V.; Demidova, Natalya D.; Bobrysheva, Natalia P.; Osmolowsky, Mikhail G.; Voznesenskiy, Mikhail A.; Osmolovskaya, Olga M.

в: Ceramics International, Том 47, № 2, 15.01.2021, стр. 2809-2821.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

BibTeX

@article{bedd5c3cc8bb4b4a9d6e0beaacc88d58,

title = "The effect of reaction medium and hydrothermal synthesis conditions on morphological parameters and thermal behavior of calcium phosphate nanoparticles",

abstract = "In this work, calcium phosphate nanoparticles were synthesized by a scalable hydrothermal method at significantly lower holding time, than was previously described in the literature. The morphological parameters of all the samples were characterized systematically by XRD, TEM, SSA, and FTIR. The lattice parameters and crystallite sizes are under discussion. It was shown that the surfactants and dopants greatly affect the nanoparticles formation process at all the stages – from the unit cell to crystallite size and nanoparticle sizes and shape. The possibility of NPs morphological parameters regulation via adding capping agents and dopants with different nature was demonstrated. Thermal properties of HAp and doped TCP nanoparticles are also reported. Results show that surfactant presence prevents sintering at high temperatures, in HAp case thermal stability depends on whether the nanoparticles are mono or polycrystalline, the presence of surfactant on the surface shifts the decomposition temperature to higher values.",

keywords = "Capping agents, Doping, Hydroxyapatite, Thermal stability, Tricalcium phosphate",

author = "Syukkalova, {Evgeniya A.} and Sadetskaya, {Anastasia V.} and Demidova, {Natalya D.} and Bobrysheva, {Natalia P.} and Osmolowsky, {Mikhail G.} and Voznesenskiy, {Mikhail A.} and Osmolovskaya, {Olga M.}",

note = "Publisher Copyright: {\textcopyright} 2020 Elsevier Ltd and Techna Group S.r.l.",

year = "2021",

month = jan,

day = "15",

doi = "10.1016/j.ceramint.2020.09.135",

language = "English",

volume = "47",

pages = "2809--2821",

journal = "Ceramics International",

issn = "0272-8842",

publisher = "Elsevier",

number = "2",

}

RIS

TY - JOUR

T1 - The effect of reaction medium and hydrothermal synthesis conditions on morphological parameters and thermal behavior of calcium phosphate nanoparticles

AU - Syukkalova, Evgeniya A.

AU - Sadetskaya, Anastasia V.

AU - Demidova, Natalya D.

AU - Bobrysheva, Natalia P.

AU - Osmolowsky, Mikhail G.

AU - Voznesenskiy, Mikhail A.

AU - Osmolovskaya, Olga M.

PY - 2021/1/15

Y1 - 2021/1/15

N2 - In this work, calcium phosphate nanoparticles were synthesized by a scalable hydrothermal method at significantly lower holding time, than was previously described in the literature. The morphological parameters of all the samples were characterized systematically by XRD, TEM, SSA, and FTIR. The lattice parameters and crystallite sizes are under discussion. It was shown that the surfactants and dopants greatly affect the nanoparticles formation process at all the stages – from the unit cell to crystallite size and nanoparticle sizes and shape. The possibility of NPs morphological parameters regulation via adding capping agents and dopants with different nature was demonstrated. Thermal properties of HAp and doped TCP nanoparticles are also reported. Results show that surfactant presence prevents sintering at high temperatures, in HAp case thermal stability depends on whether the nanoparticles are mono or polycrystalline, the presence of surfactant on the surface shifts the decomposition temperature to higher values.

AB - In this work, calcium phosphate nanoparticles were synthesized by a scalable hydrothermal method at significantly lower holding time, than was previously described in the literature. The morphological parameters of all the samples were characterized systematically by XRD, TEM, SSA, and FTIR. The lattice parameters and crystallite sizes are under discussion. It was shown that the surfactants and dopants greatly affect the nanoparticles formation process at all the stages – from the unit cell to crystallite size and nanoparticle sizes and shape. The possibility of NPs morphological parameters regulation via adding capping agents and dopants with different nature was demonstrated. Thermal properties of HAp and doped TCP nanoparticles are also reported. Results show that surfactant presence prevents sintering at high temperatures, in HAp case thermal stability depends on whether the nanoparticles are mono or polycrystalline, the presence of surfactant on the surface shifts the decomposition temperature to higher values.

KW - Capping agents

KW - Doping

KW - Hydroxyapatite

KW - Thermal stability

KW - Tricalcium phosphate

UR - http://www.scopus.com/inward/record.url?scp=85092013759&partnerID=8YFLogxK

U2 - 10.1016/j.ceramint.2020.09.135

DO - 10.1016/j.ceramint.2020.09.135

M3 - Article

AN - SCOPUS:85092013759

VL - 47

SP - 2809

EP - 2821

JO - Ceramics International

JF - Ceramics International

SN - 0272-8842

IS - 2

ER -

ID: 62722889