Результаты исследований: Научные публикации в периодических изданиях › Обзорная статья › Рецензирование
The crystal structure of averievite, Cu5O2(VO4)2·nMX : Comparison with related compounds. / Starova, G. L.; Krivovichev, S. V.; Fundamensky, V. S.; Filatov, S. K.
в: Mineralogical Magazine, Том 61, № 3, 01.06.1997, стр. 441-446.Результаты исследований: Научные публикации в периодических изданиях › Обзорная статья › Рецензирование
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TY - JOUR
T1 - The crystal structure of averievite, Cu5O2(VO4)2·nMX
T2 - Comparison with related compounds
AU - Starova, G. L.
AU - Krivovichev, S. V.
AU - Fundamensky, V. S.
AU - Filatov, S. K.
PY - 1997/6/1
Y1 - 1997/6/1
N2 - The crystal structure of averievite, Cu5O2(VO4)2·nMX has been determined. Trigonal system, space group P3, a = 6.375(1), c = 8.399(1) Å, V = 295.6(1) Å3, Z = 1, Dx = 4.01(1) g/cm3. The atomic arrangement is characterized by infinite nets parallel to (001) composed of [OCu4]6+ tetrahedra linked via corners in hexagonal rings. The bases of neigbouring tetrahedra are in one plane and their non-shared corners are turned to the opposite sides. The [VO4]3- tetrahedra are attached to the bases of [OCu4] tetrahedra. There are large (R >3.2 Å) channels in the structure where large molecular particles can enter. The comparison of the averievite structure with related compounds (in particular, copper oxovanadates) is given from the point of view of [OT4] polyion crystal chemistry.
AB - The crystal structure of averievite, Cu5O2(VO4)2·nMX has been determined. Trigonal system, space group P3, a = 6.375(1), c = 8.399(1) Å, V = 295.6(1) Å3, Z = 1, Dx = 4.01(1) g/cm3. The atomic arrangement is characterized by infinite nets parallel to (001) composed of [OCu4]6+ tetrahedra linked via corners in hexagonal rings. The bases of neigbouring tetrahedra are in one plane and their non-shared corners are turned to the opposite sides. The [VO4]3- tetrahedra are attached to the bases of [OCu4] tetrahedra. There are large (R >3.2 Å) channels in the structure where large molecular particles can enter. The comparison of the averievite structure with related compounds (in particular, copper oxovanadates) is given from the point of view of [OT4] polyion crystal chemistry.
KW - Averievite
KW - Crystal structure
UR - http://www.scopus.com/inward/record.url?scp=0030698397&partnerID=8YFLogxK
M3 - Review article
AN - SCOPUS:0030698397
VL - 61
SP - 441
EP - 446
JO - Mineralogical Magazine
JF - Mineralogical Magazine
SN - 0026-461X
IS - 3
ER -
ID: 53955540