Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
The condition of the phase equilibrium of a soluble nanoparticle. / Rusanov, A. I.
в: Colloid Journal, Том 68, № 3, 01.05.2006, стр. 334-340.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - The condition of the phase equilibrium of a soluble nanoparticle
AU - Rusanov, A. I.
PY - 2006/5/1
Y1 - 2006/5/1
N2 - The condition of the phase equilibrium of an amorphous nanoparticle and a nanocrystal is derived with allowance for a possible presence of movable components in a solid body and the dependence of thermodynamic surface tension on the surface curvature. With the use of dispersion forces as an example, it is demonstrated by direct calculation that a correction to the Gibbs formula for the variations of surface tension can be substantial for nanoparticles that approach molecular sizes.
AB - The condition of the phase equilibrium of an amorphous nanoparticle and a nanocrystal is derived with allowance for a possible presence of movable components in a solid body and the dependence of thermodynamic surface tension on the surface curvature. With the use of dispersion forces as an example, it is demonstrated by direct calculation that a correction to the Gibbs formula for the variations of surface tension can be substantial for nanoparticles that approach molecular sizes.
UR - http://www.scopus.com/inward/record.url?scp=33744959297&partnerID=8YFLogxK
U2 - 10.1134/S1061933X06030112
DO - 10.1134/S1061933X06030112
M3 - Article
AN - SCOPUS:33744959297
VL - 68
SP - 334
EP - 340
JO - Colloid Journal
JF - Colloid Journal
SN - 1061-933X
IS - 3
ER -
ID: 51305371