Standard

The Assembly of Unique Hexanuclear Copper(I) Complexes with Effective White Luminescence. / Strelnik, Igor D. ; Dayanova, Irina R.; Kolesnikov, Ilya E. ; Fayzullin, Robert R.; Litvinov, Igor A.; Samigullina, Aida I.; Gerasimova, Tatiana P.; Katsyuba, Sergey A.; Musina, Elvira I.; Karasik, Andrey A.

в: Inorganic Chemistry, Том 58, № 2, 2019, стр. 1048-1057.

Результаты исследований: Научные публикации в периодических изданияхстатьяРецензирование

Harvard

Strelnik, ID, Dayanova, IR, Kolesnikov, IE, Fayzullin, RR, Litvinov, IA, Samigullina, AI, Gerasimova, TP, Katsyuba, SA, Musina, EI & Karasik, AA 2019, 'The Assembly of Unique Hexanuclear Copper(I) Complexes with Effective White Luminescence', Inorganic Chemistry, Том. 58, № 2, стр. 1048-1057. https://doi.org/10.1021/acs.inorgchem.8b01862

APA

Strelnik, I. D., Dayanova, I. R., Kolesnikov, I. E., Fayzullin, R. R., Litvinov, I. A., Samigullina, A. I., Gerasimova, T. P., Katsyuba, S. A., Musina, E. I., & Karasik, A. A. (2019). The Assembly of Unique Hexanuclear Copper(I) Complexes with Effective White Luminescence. Inorganic Chemistry, 58(2), 1048-1057. https://doi.org/10.1021/acs.inorgchem.8b01862

Vancouver

Strelnik ID, Dayanova IR, Kolesnikov IE, Fayzullin RR, Litvinov IA, Samigullina AI и пр. The Assembly of Unique Hexanuclear Copper(I) Complexes with Effective White Luminescence. Inorganic Chemistry. 2019;58(2):1048-1057. https://doi.org/10.1021/acs.inorgchem.8b01862

Author

Strelnik, Igor D. ; Dayanova, Irina R. ; Kolesnikov, Ilya E. ; Fayzullin, Robert R. ; Litvinov, Igor A. ; Samigullina, Aida I. ; Gerasimova, Tatiana P. ; Katsyuba, Sergey A. ; Musina, Elvira I. ; Karasik, Andrey A. / The Assembly of Unique Hexanuclear Copper(I) Complexes with Effective White Luminescence. в: Inorganic Chemistry. 2019 ; Том 58, № 2. стр. 1048-1057.

BibTeX

@article{b998d91ee5c64c0999f8216adaf398d0,
title = "The Assembly of Unique Hexanuclear Copper(I) Complexes with Effective White Luminescence",
abstract = "The unique L 2 Cu 6 I 6 complexes containing two Cu 3 I 3 units have been obtained via reaction of 1,5-diaza-3,7-diphosphacyclooctanes bearing ethylpyridyl substituents at phosphorus atoms with an excess of copper iodide. The structure of one of the complexes was confirmed by X-ray diffraction. It was shown that the complexes can exist in two crystalline phases with different parameters of the unit cell, which were detected by the PXRD data analyses. The solvent-free crystalline phases of the complexes display rare solid-state white emission at room temperature, which is observed due to the presence of two broad bands in the emission spectra with maxima at 464 and 610 nm. Quantum chemical computations show that the high-energy band has 3 (M+X)LCT origin, whereas the low-energy band is interpreted as 3 CC. The quantum yields of white luminescence of complexes reach 15-20%. ",
author = "Strelnik, {Igor D.} and Dayanova, {Irina R.} and Kolesnikov, {Ilya E.} and Fayzullin, {Robert R.} and Litvinov, {Igor A.} and Samigullina, {Aida I.} and Gerasimova, {Tatiana P.} and Katsyuba, {Sergey A.} and Musina, {Elvira I.} and Karasik, {Andrey A.}",
year = "2019",
doi = "10.1021/acs.inorgchem.8b01862",
language = "English",
volume = "58",
pages = "1048--1057",
journal = "Inorganic Chemistry",
issn = "0020-1669",
publisher = "American Chemical Society",
number = "2",

}

RIS

TY - JOUR

T1 - The Assembly of Unique Hexanuclear Copper(I) Complexes with Effective White Luminescence

AU - Strelnik, Igor D.

AU - Dayanova, Irina R.

AU - Kolesnikov, Ilya E.

AU - Fayzullin, Robert R.

AU - Litvinov, Igor A.

AU - Samigullina, Aida I.

AU - Gerasimova, Tatiana P.

AU - Katsyuba, Sergey A.

AU - Musina, Elvira I.

AU - Karasik, Andrey A.

PY - 2019

Y1 - 2019

N2 - The unique L 2 Cu 6 I 6 complexes containing two Cu 3 I 3 units have been obtained via reaction of 1,5-diaza-3,7-diphosphacyclooctanes bearing ethylpyridyl substituents at phosphorus atoms with an excess of copper iodide. The structure of one of the complexes was confirmed by X-ray diffraction. It was shown that the complexes can exist in two crystalline phases with different parameters of the unit cell, which were detected by the PXRD data analyses. The solvent-free crystalline phases of the complexes display rare solid-state white emission at room temperature, which is observed due to the presence of two broad bands in the emission spectra with maxima at 464 and 610 nm. Quantum chemical computations show that the high-energy band has 3 (M+X)LCT origin, whereas the low-energy band is interpreted as 3 CC. The quantum yields of white luminescence of complexes reach 15-20%.

AB - The unique L 2 Cu 6 I 6 complexes containing two Cu 3 I 3 units have been obtained via reaction of 1,5-diaza-3,7-diphosphacyclooctanes bearing ethylpyridyl substituents at phosphorus atoms with an excess of copper iodide. The structure of one of the complexes was confirmed by X-ray diffraction. It was shown that the complexes can exist in two crystalline phases with different parameters of the unit cell, which were detected by the PXRD data analyses. The solvent-free crystalline phases of the complexes display rare solid-state white emission at room temperature, which is observed due to the presence of two broad bands in the emission spectra with maxima at 464 and 610 nm. Quantum chemical computations show that the high-energy band has 3 (M+X)LCT origin, whereas the low-energy band is interpreted as 3 CC. The quantum yields of white luminescence of complexes reach 15-20%.

UR - http://www.scopus.com/inward/record.url?scp=85060300398&partnerID=8YFLogxK

U2 - 10.1021/acs.inorgchem.8b01862

DO - 10.1021/acs.inorgchem.8b01862

M3 - Article

VL - 58

SP - 1048

EP - 1057

JO - Inorganic Chemistry

JF - Inorganic Chemistry

SN - 0020-1669

IS - 2

ER -

ID: 49770278