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DOI

Analytical expressions for the direct and reverse fluxes of molecular aggregates over the first and second potential barriers of the aggregation work in the presence of spherical and cylindrical micelles in non-ionic surfactant solution were derived. Expressions for the sum (entering into kinetic equations of micellization) of direct and reverse fluxes of molecular aggregates over the first and second potential barriers of the aggregation work in the vicinity of the final equilibrium state of materially isolated surfactant solution were linearized. In the experimentally important range of the values of overall surfactant concentration in solution where the predominant contribution to the total surfactant amount is introduced by cylindrical micelles, we derived a closed system of two linearized relaxation equations determining the buildup (with time) of experimentally observed total concentrations of spherical and cylindrical micelles in the vicinity of the final equilibrium state of materially isolated surfactant solution. The case of the solutions of such surfactants, for which the spherical shape of a micelle appeared to be unrealizable due to the structure and packing conditions of molecules, was considered separately.

Переведенное названиеСИСТЕМА РЕЛАКСАЦИОННЫХ УРАВНЕНИЙ ДЛЯ МАТЕРИАЛЬНО ИЗОЛИРОВАННОГО РАСТВОРА ПАВ СО СФЕРИЧЕСКИМИ И ЦИЛИНДРИЧЕСКИМИ МИЦЕЛЛАМИ
Язык оригиналаанглийский
Страницы (с-по)32-40
Число страниц9
ЖурналColloid Journal
Том67
Номер выпуска1
DOI
СостояниеОпубликовано - 1 янв 2005

    Предметные области Scopus

  • Поверхности и интерфейсы
  • Физическая и теоретическая химия
  • Коллоидная химия и химия поверхности

ID: 5013399