TY - JOUR

T1 - Synthesis, Structure, and Properties of Rhodium(II) Acetate Complexes with 2H-Azirines

AU - Ростовский, Николай Витальевич

AU - Филиппов, Илья Павлович

AU - Гришин, Александр Валерьевич

PY - 2024/3/21

Y1 - 2024/3/21

N2 - Complexes of rhodium(II) acetate with 2H-azirines were obtained for the first time. The 1 : 2 complexes were characterized using 1H and 13C NMR, IR, and UV spectroscopy and high-resolution mass spectrometry. The structure of Rh2(OAc)4 complex with two 3-(4-methoxyphenyl)-2H-azirine molecules was studied by X-ray diffraction analysis. In crystal, the molecule of this complex belongs to the Ci point group.

AB - Complexes of rhodium(II) acetate with 2H-azirines were obtained for the first time. The 1 : 2 complexes were characterized using 1H and 13C NMR, IR, and UV spectroscopy and high-resolution mass spectrometry. The structure of Rh2(OAc)4 complex with two 3-(4-methoxyphenyl)-2H-azirine molecules was studied by X-ray diffraction analysis. In crystal, the molecule of this complex belongs to the Ci point group.

KW - 2H-azirines

KW - X-ray diffraction analysis

KW - metal complex

KW - rhodium(II) acetate

KW - spectroscopy

UR - https://www.mendeley.com/catalogue/d37ad58a-3f5d-3af7-95b9-5919b3146bb8/

U2 - 10.1134/s107036322414007x

DO - 10.1134/s107036322414007x

M3 - Article

VL - 94

SP - S47–S52

JO - Russian Journal of General Chemistry

JF - Russian Journal of General Chemistry

SN - 1070-3632

IS - Suppl 1

ER -