Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Synthesis of Mono- and Disaccharide 4-[(ω-Sulfanylalkyl)oxy]benzoylhydrazones as Potential Glycoligands for Noble Metal Nanoparticles. / Ershov, A. Yu; Martynenkov, A. A.; Lagoda, I. V.; Yakimansky, A. V.
в: Russian Journal of General Chemistry, Том 89, № 2, 01.02.2019, стр. 292-299.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Synthesis of Mono- and Disaccharide 4-[(ω-Sulfanylalkyl)oxy]benzoylhydrazones as Potential Glycoligands for Noble Metal Nanoparticles
AU - Ershov, A. Yu
AU - Martynenkov, A. A.
AU - Lagoda, I. V.
AU - Yakimansky, A. V.
PY - 2019/2/1
Y1 - 2019/2/1
N2 - A procedure has been developed for the synthesis of previously unknown aldose 4-[(ω-sulfanylalkyl) oxy]benzoylhydrazones (where alkyl is hexyl or decyl and aldoses are D-glucose, D-galactose, D-maltose, and D-lactose) that a repromising glycoligands for noble metal nanoparticles. According to the 1 H and 13 C NMR data, 4-[(ω-sulfanylalkyl)oxy]benzoylhydrazones derived from D-glucose, D-maltose, and D-lactose in crystal and in DMSO-d 6 solution have exclusively the cyclic pyranose structure (α- and β-anomers). D-Galactose 4-[(ω-sulfanylalkyl)oxy]benzoylhydrazones in DMSO-d 6 solution exist as tautomeric mixtures of cyclic pyranose and open-chain acylhydrazone structures.
AB - A procedure has been developed for the synthesis of previously unknown aldose 4-[(ω-sulfanylalkyl) oxy]benzoylhydrazones (where alkyl is hexyl or decyl and aldoses are D-glucose, D-galactose, D-maltose, and D-lactose) that a repromising glycoligands for noble metal nanoparticles. According to the 1 H and 13 C NMR data, 4-[(ω-sulfanylalkyl)oxy]benzoylhydrazones derived from D-glucose, D-maltose, and D-lactose in crystal and in DMSO-d 6 solution have exclusively the cyclic pyranose structure (α- and β-anomers). D-Galactose 4-[(ω-sulfanylalkyl)oxy]benzoylhydrazones in DMSO-d 6 solution exist as tautomeric mixtures of cyclic pyranose and open-chain acylhydrazone structures.
KW - ring—chain tautomerism
KW - thiol-containing mono- and disaccharide acylhydrazones
UR - http://www.scopus.com/inward/record.url?scp=85063995174&partnerID=8YFLogxK
U2 - 10.1134/S1070363219020208
DO - 10.1134/S1070363219020208
M3 - Article
AN - SCOPUS:85063995174
VL - 89
SP - 292
EP - 299
JO - Russian Journal of General Chemistry
JF - Russian Journal of General Chemistry
SN - 1070-3632
IS - 2
ER -
ID: 50556409