Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Synthesis of Mixed-Ligand Nitrileand Carbonyl–Isocyanide Complexes of Platinum(II) and Their Reaction with P-Toluenesulfonyl Hydrazide. / Popov, R. A.; Novikov, A. S.; Mikherdov, A. S.
в: Russian Journal of General Chemistry, Том 88, № 11, 01.11.2018, стр. 2347-2353.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Synthesis of Mixed-Ligand Nitrileand Carbonyl–Isocyanide Complexes of Platinum(II) and Their Reaction with P-Toluenesulfonyl Hydrazide
AU - Popov, R. A.
AU - Novikov, A. S.
AU - Mikherdov, A. S.
PY - 2018/11/1
Y1 - 2018/11/1
N2 - Mixed-ligand nitrile- and carbonyl-isocyanide complexes of platinum(II) trans-[PtCl2(NCEt)CNXyl] and trans-[PtCl2(CO)CNXyl] (Xyl = 2,6-Me2C6H3) have been prepared for the first time. The compounds have been characterized by mass spectrometry, IR and NMR spectroscopy. Reactivity of the prepared complexes towards N-nucleophiles has been studied using the reaction with p-toluenesulfonyl hydrazide as the example.
AB - Mixed-ligand nitrile- and carbonyl-isocyanide complexes of platinum(II) trans-[PtCl2(NCEt)CNXyl] and trans-[PtCl2(CO)CNXyl] (Xyl = 2,6-Me2C6H3) have been prepared for the first time. The compounds have been characterized by mass spectrometry, IR and NMR spectroscopy. Reactivity of the prepared complexes towards N-nucleophiles has been studied using the reaction with p-toluenesulfonyl hydrazide as the example.
KW - carbonyl complexes
KW - Hirshfeld surface analysis
KW - isocyanide complexes
KW - nitrile complexes
KW - platinum complexes
UR - http://www.scopus.com/inward/record.url?scp=85059155036&partnerID=8YFLogxK
U2 - 10.1134/S1070363218110166
DO - 10.1134/S1070363218110166
M3 - Article
AN - SCOPUS:85059155036
VL - 88
SP - 2347
EP - 2353
JO - Russian Journal of General Chemistry
JF - Russian Journal of General Chemistry
SN - 1070-3632
IS - 11
ER -
ID: 36990109