Standard

Synthesis of Isoxazolo[5',4':3,4]pyrrolo[1,2-a]azepines via N-Acyliminium Cyclization. / Lenshmidt, L. V. ; Ledovskaya, M. S. ; Larina, A. G. ; Filatov, A. S. ; Chakchir, O. B. ; Stepakov, A. V. .

в: Russian Journal of Organic Chemistry, Том 56, № 2, 04.2020, стр. 234-245.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

Harvard

Lenshmidt, LV, Ledovskaya, MS, Larina, AG, Filatov, AS, Chakchir, OB & Stepakov, AV 2020, 'Synthesis of Isoxazolo[5',4':3,4]pyrrolo[1,2-a]azepines via N-Acyliminium Cyclization', Russian Journal of Organic Chemistry, Том. 56, № 2, стр. 234-245. https://doi.org/10.1134/S1070428020020098

APA

Lenshmidt, L. V., Ledovskaya, M. S., Larina, A. G., Filatov, A. S., Chakchir, O. B., & Stepakov, A. V. (2020). Synthesis of Isoxazolo[5',4':3,4]pyrrolo[1,2-a]azepines via N-Acyliminium Cyclization. Russian Journal of Organic Chemistry, 56(2), 234-245. https://doi.org/10.1134/S1070428020020098

Vancouver

Lenshmidt LV, Ledovskaya MS, Larina AG, Filatov AS, Chakchir OB, Stepakov AV. Synthesis of Isoxazolo[5',4':3,4]pyrrolo[1,2-a]azepines via N-Acyliminium Cyclization. Russian Journal of Organic Chemistry. 2020 Апр.;56(2):234-245. https://doi.org/10.1134/S1070428020020098

Author

Lenshmidt, L. V. ; Ledovskaya, M. S. ; Larina, A. G. ; Filatov, A. S. ; Chakchir, O. B. ; Stepakov, A. V. . / Synthesis of Isoxazolo[5',4':3,4]pyrrolo[1,2-a]azepines via N-Acyliminium Cyclization. в: Russian Journal of Organic Chemistry. 2020 ; Том 56, № 2. стр. 234-245.

BibTeX

@article{53d08c702f844de4843f81cb06711810,
title = "Synthesis of Isoxazolo[5',4':3,4]pyrrolo[1,2-a]azepines via N-Acyliminium Cyclization",
abstract = "Fused polycyclic compounds with benzo[c]isoxazolo[5',4':3,4]pyrrolo[1,2-a]azepine, dibenzo[c,e]isoxazolo[5',4':3,4]pyrrolo[1,2-a]azepine, and benzo[f]isoxazolo[5',4':3,4]pyrrolo[1,2-d]oxazepine cores are readily available via cyclization of the N-acyliminium cation generated from the corresponding 6-hydoxy-5-R-6,6a-dihydro-3aH-pyrrolo[3,4-d]isoxazol-4(5H)-ones in the presence of BF3·Et2O or Sn(NTf2)4.",
keywords = "N-acyliminium cyclization, pyrrolo[2,1-a]azepines, hydroxylactams, isoxazolines, Lewis acid, stereselective reaction, chemoselective reduction, 1,3-dipolar cycloaddition, SODIUM, 3-dipolar cycloaddition, ION, ISOXAZOLOPYRROLOISOQUINOLINES, 1-a]azepines, STEMONA ALKALOIDS, 1, ROOTS, pyrrolo[2, DERIVATIVES",
author = "Lenshmidt, {L. V.} and Ledovskaya, {M. S.} and Larina, {A. G.} and Filatov, {A. S.} and Chakchir, {O. B.} and Stepakov, {A. V.}",
note = "Publisher Copyright: {\textcopyright} 2020, Pleiades Publishing, Ltd.",
year = "2020",
month = apr,
doi = "10.1134/S1070428020020098",
language = "English",
volume = "56",
pages = "234--245",
journal = "Russian Journal of Organic Chemistry",
issn = "1070-4280",
publisher = "МАИК {"}Наука/Интерпериодика{"}",
number = "2",

}

RIS

TY - JOUR

T1 - Synthesis of Isoxazolo[5',4':3,4]pyrrolo[1,2-a]azepines via N-Acyliminium Cyclization

AU - Lenshmidt, L. V.

AU - Ledovskaya, M. S.

AU - Larina, A. G.

AU - Filatov, A. S.

AU - Chakchir, O. B.

AU - Stepakov, A. V.

N1 - Publisher Copyright: © 2020, Pleiades Publishing, Ltd.

PY - 2020/4

Y1 - 2020/4

N2 - Fused polycyclic compounds with benzo[c]isoxazolo[5',4':3,4]pyrrolo[1,2-a]azepine, dibenzo[c,e]isoxazolo[5',4':3,4]pyrrolo[1,2-a]azepine, and benzo[f]isoxazolo[5',4':3,4]pyrrolo[1,2-d]oxazepine cores are readily available via cyclization of the N-acyliminium cation generated from the corresponding 6-hydoxy-5-R-6,6a-dihydro-3aH-pyrrolo[3,4-d]isoxazol-4(5H)-ones in the presence of BF3·Et2O or Sn(NTf2)4.

AB - Fused polycyclic compounds with benzo[c]isoxazolo[5',4':3,4]pyrrolo[1,2-a]azepine, dibenzo[c,e]isoxazolo[5',4':3,4]pyrrolo[1,2-a]azepine, and benzo[f]isoxazolo[5',4':3,4]pyrrolo[1,2-d]oxazepine cores are readily available via cyclization of the N-acyliminium cation generated from the corresponding 6-hydoxy-5-R-6,6a-dihydro-3aH-pyrrolo[3,4-d]isoxazol-4(5H)-ones in the presence of BF3·Et2O or Sn(NTf2)4.

KW - N-acyliminium cyclization

KW - pyrrolo[2,1-a]azepines

KW - hydroxylactams

KW - isoxazolines

KW - Lewis acid

KW - stereselective reaction

KW - chemoselective reduction

KW - 1,3-dipolar cycloaddition

KW - SODIUM

KW - 3-dipolar cycloaddition

KW - ION

KW - ISOXAZOLOPYRROLOISOQUINOLINES

KW - 1-a]azepines

KW - STEMONA ALKALOIDS

KW - 1

KW - ROOTS

KW - pyrrolo[2

KW - DERIVATIVES

UR - http://www.scopus.com/inward/record.url?scp=85083326344&partnerID=8YFLogxK

UR - https://www.mendeley.com/catalogue/e039987a-7318-398c-8be5-69ee12914134/

U2 - 10.1134/S1070428020020098

DO - 10.1134/S1070428020020098

M3 - Article

VL - 56

SP - 234

EP - 245

JO - Russian Journal of Organic Chemistry

JF - Russian Journal of Organic Chemistry

SN - 1070-4280

IS - 2

ER -

ID: 70822954