Synthesis of [99TcX(CO)5] (X = Cl, Br, I) at ambient pressure › Научные исследования в СПбГУ

Standard

Synthesis of [⁹⁹TcX(CO)₅] (X = Cl, Br, I) at ambient pressure. / Miroslavov, Alexander E.; Braband, Henrik; Sidorenko, Georgii V.; Stepanova, Ekaterina S.; Lumpov, Alexander A.; Alberto, Roger.

в: Journal of Organometallic Chemistry, Том 871, 15.09.2018, стр. 56-59.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

Harvard

Miroslavov, AE, Braband, H, Sidorenko, GV, Stepanova, ES, Lumpov, AA & Alberto, R 2018, 'Synthesis of [⁹⁹TcX(CO)₅] (X = Cl, Br, I) at ambient pressure', Journal of Organometallic Chemistry, Том. 871, стр. 56-59. https://doi.org/10.1016/j.jorganchem.2018.06.028

APA

Miroslavov, A. E., Braband, H., Sidorenko, G. V., Stepanova, E. S., Lumpov, A. A., & Alberto, R. (2018). Synthesis of [⁹⁹TcX(CO)₅] (X = Cl, Br, I) at ambient pressure. Journal of Organometallic Chemistry, 871, 56-59. https://doi.org/10.1016/j.jorganchem.2018.06.028

Vancouver

Miroslavov AE, Braband H, Sidorenko GV, Stepanova ES, Lumpov AA, Alberto R. Synthesis of [⁹⁹TcX(CO)₅] (X = Cl, Br, I) at ambient pressure. Journal of Organometallic Chemistry. 2018 Сент. 15;871:56-59. https://doi.org/10.1016/j.jorganchem.2018.06.028

Author

Miroslavov, Alexander E. ; Braband, Henrik ; Sidorenko, Georgii V. ; Stepanova, Ekaterina S. ; Lumpov, Alexander A. ; Alberto, Roger. / Synthesis of [⁹⁹TcX(CO)₅] (X = Cl, Br, I) at ambient pressure. в: Journal of Organometallic Chemistry. 2018 ; Том 871. стр. 56-59.

BibTeX

@article{846dc1efdc6c4f809a65bf861ef605c2,

title = "Synthesis of [99TcX(CO)5] (X = Cl, Br, I) at ambient pressure",

abstract = "A novel procedure for ambient-pressure synthesis of pentacarbonyltechnetium halides [99TcX(CO)5] (X = Cl, Br) was developed. The procedure is based on treatment of K2[99TcX6] with a mixture of HCOOH and H2SO4 on heating. With X = I, a mixture of [99TcI(CO)5] and [99TcI(CO)4]2 was obtained. The products were characterized by elemental analysis and by 99Tc NMR and IR spectroscopy.",

keywords = "Ambient-pressure synthesis, Pentacarbonylrhenium halides, Pentacarbonyltechnetium halides",

author = "Miroslavov, {Alexander E.} and Henrik Braband and Sidorenko, {Georgii V.} and Stepanova, {Ekaterina S.} and Lumpov, {Alexander A.} and Roger Alberto",

year = "2018",

month = sep,

day = "15",

doi = "10.1016/j.jorganchem.2018.06.028",

language = "English",

volume = "871",

pages = "56--59",

journal = "Journal of Organometallic Chemistry",

issn = "0022-328X",

publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Synthesis of [99TcX(CO)5] (X = Cl, Br, I) at ambient pressure

AU - Miroslavov, Alexander E.

AU - Braband, Henrik

AU - Sidorenko, Georgii V.

AU - Stepanova, Ekaterina S.

AU - Lumpov, Alexander A.

AU - Alberto, Roger

PY - 2018/9/15

Y1 - 2018/9/15

N2 - A novel procedure for ambient-pressure synthesis of pentacarbonyltechnetium halides [99TcX(CO)5] (X = Cl, Br) was developed. The procedure is based on treatment of K2[99TcX6] with a mixture of HCOOH and H2SO4 on heating. With X = I, a mixture of [99TcI(CO)5] and [99TcI(CO)4]2 was obtained. The products were characterized by elemental analysis and by 99Tc NMR and IR spectroscopy.

AB - A novel procedure for ambient-pressure synthesis of pentacarbonyltechnetium halides [99TcX(CO)5] (X = Cl, Br) was developed. The procedure is based on treatment of K2[99TcX6] with a mixture of HCOOH and H2SO4 on heating. With X = I, a mixture of [99TcI(CO)5] and [99TcI(CO)4]2 was obtained. The products were characterized by elemental analysis and by 99Tc NMR and IR spectroscopy.

KW - Ambient-pressure synthesis

KW - Pentacarbonylrhenium halides

KW - Pentacarbonyltechnetium halides

UR - http://www.scopus.com/inward/record.url?scp=85049759803&partnerID=8YFLogxK

U2 - 10.1016/j.jorganchem.2018.06.028

DO - 10.1016/j.jorganchem.2018.06.028

M3 - Article

AN - SCOPUS:85049759803

VL - 871

SP - 56

EP - 59

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

SN - 0022-328X

ER -

ID: 76834324