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Synthesis, characterization and photophysical properties of gold(I)-copper(I) alkynyl clusters with 1,4-bis(diphenylphosphino)butane, effect of the diphosphine ligand on luminescence characteristics. / Krytchankou, I.S.; Krupenya, D.V.; Gurzhiy, V.V.; Belyaev, A.A.; Karttunen, A.J.; Koshevoy, I.O.; Melnikov, A.S.; Tunik, S.P.

в: Journal of Organometallic Chemistry, 2013, стр. 65-71.

Результаты исследований: Научные публикации в периодических изданиях › статья

Harvard

Krytchankou, IS, Krupenya, DV, Gurzhiy, VV, Belyaev, AA, Karttunen, AJ, Koshevoy, IO, Melnikov, AS & Tunik, SP 2013, 'Synthesis, characterization and photophysical properties of gold(I)-copper(I) alkynyl clusters with 1,4-bis(diphenylphosphino)butane, effect of the diphosphine ligand on luminescence characteristics', Journal of Organometallic Chemistry, стр. 65-71. https://doi.org/10.1016/j.jorganchem.2012.09.003

APA

Krytchankou, I. S., Krupenya, D. V., Gurzhiy, V. V., Belyaev, A. A., Karttunen, A. J., Koshevoy, I. O., Melnikov, A. S., & Tunik, S. P. (2013). Synthesis, characterization and photophysical properties of gold(I)-copper(I) alkynyl clusters with 1,4-bis(diphenylphosphino)butane, effect of the diphosphine ligand on luminescence characteristics. Journal of Organometallic Chemistry, 65-71. https://doi.org/10.1016/j.jorganchem.2012.09.003

Vancouver

Krytchankou IS, Krupenya DV, Gurzhiy VV, Belyaev AA, Karttunen AJ, Koshevoy IO и пр. Synthesis, characterization and photophysical properties of gold(I)-copper(I) alkynyl clusters with 1,4-bis(diphenylphosphino)butane, effect of the diphosphine ligand on luminescence characteristics. Journal of Organometallic Chemistry. 2013;65-71. https://doi.org/10.1016/j.jorganchem.2012.09.003

Author

Krytchankou, I.S. ; Krupenya, D.V. ; Gurzhiy, V.V. ; Belyaev, A.A. ; Karttunen, A.J. ; Koshevoy, I.O. ; Melnikov, A.S. ; Tunik, S.P. / Synthesis, characterization and photophysical properties of gold(I)-copper(I) alkynyl clusters with 1,4-bis(diphenylphosphino)butane, effect of the diphosphine ligand on luminescence characteristics. в: Journal of Organometallic Chemistry. 2013 ; стр. 65-71.

BibTeX

@article{d8b08cc3dce54a81853fb9f9e72f1ac7,
title = "Synthesis, characterization and photophysical properties of gold(I)-copper(I) alkynyl clusters with 1,4-bis(diphenylphosphino)butane, effect of the diphosphine ligand on luminescence characteristics",
abstract = "Reactions of the {AuC2R}n polymer (R = -C 6H4NO2, -C6H5, -C 6H4Ph, -C6H4OMe, -C 6H4NMe2, -C(OH)Me2, -C 6H10(OH)) with stoichiometric amount of 1,4-bis(diphenylphosphino)butane and Cu(I) ions afford the dicationic complexes of general formula [Au6Cu2(C2-R) 6(PPh2(CH2)4PPh2) 3](PF6)2. The compounds obtained (1-7) display common {"}rods-in-belt{"} structural motif with the {"}Cu 2{Au(C2R)2}3{"} central cluster core wrapped about by the {Au3(Ph2P(CH2) 4PPh2)3} belt. This structural pattern was revealed in solid state by X-ray crystallography and confirmed in solution using the NMR spectroscopy. The complexes 6 and 7 containing hydroxyl substituents in the alkynyl ligands demonstrate structural distortions due to hydrogen bonding inside the cluster core. All complexes studied exhibit intense phosphorescence in dichloromethane solution, the characteristics of which depend on donor ability of the alkynyl ligand substituents. Comparison of the emission wavelengths in 1-7 with those observed in the congeners based on the arom",
author = "I.S. Krytchankou and D.V. Krupenya and V.V. Gurzhiy and A.A. Belyaev and A.J. Karttunen and I.O. Koshevoy and A.S. Melnikov and S.P. Tunik",
year = "2013",
doi = "10.1016/j.jorganchem.2012.09.003",
language = "English",
pages = "65--71",
journal = "Journal of Organometallic Chemistry",
issn = "0022-328X",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Synthesis, characterization and photophysical properties of gold(I)-copper(I) alkynyl clusters with 1,4-bis(diphenylphosphino)butane, effect of the diphosphine ligand on luminescence characteristics

AU - Krytchankou, I.S.

AU - Krupenya, D.V.

AU - Gurzhiy, V.V.

AU - Belyaev, A.A.

AU - Karttunen, A.J.

AU - Koshevoy, I.O.

AU - Melnikov, A.S.

AU - Tunik, S.P.

PY - 2013

Y1 - 2013

N2 - Reactions of the {AuC2R}n polymer (R = -C 6H4NO2, -C6H5, -C 6H4Ph, -C6H4OMe, -C 6H4NMe2, -C(OH)Me2, -C 6H10(OH)) with stoichiometric amount of 1,4-bis(diphenylphosphino)butane and Cu(I) ions afford the dicationic complexes of general formula [Au6Cu2(C2-R) 6(PPh2(CH2)4PPh2) 3](PF6)2. The compounds obtained (1-7) display common "rods-in-belt" structural motif with the "Cu 2{Au(C2R)2}3" central cluster core wrapped about by the {Au3(Ph2P(CH2) 4PPh2)3} belt. This structural pattern was revealed in solid state by X-ray crystallography and confirmed in solution using the NMR spectroscopy. The complexes 6 and 7 containing hydroxyl substituents in the alkynyl ligands demonstrate structural distortions due to hydrogen bonding inside the cluster core. All complexes studied exhibit intense phosphorescence in dichloromethane solution, the characteristics of which depend on donor ability of the alkynyl ligand substituents. Comparison of the emission wavelengths in 1-7 with those observed in the congeners based on the arom

AB - Reactions of the {AuC2R}n polymer (R = -C 6H4NO2, -C6H5, -C 6H4Ph, -C6H4OMe, -C 6H4NMe2, -C(OH)Me2, -C 6H10(OH)) with stoichiometric amount of 1,4-bis(diphenylphosphino)butane and Cu(I) ions afford the dicationic complexes of general formula [Au6Cu2(C2-R) 6(PPh2(CH2)4PPh2) 3](PF6)2. The compounds obtained (1-7) display common "rods-in-belt" structural motif with the "Cu 2{Au(C2R)2}3" central cluster core wrapped about by the {Au3(Ph2P(CH2) 4PPh2)3} belt. This structural pattern was revealed in solid state by X-ray crystallography and confirmed in solution using the NMR spectroscopy. The complexes 6 and 7 containing hydroxyl substituents in the alkynyl ligands demonstrate structural distortions due to hydrogen bonding inside the cluster core. All complexes studied exhibit intense phosphorescence in dichloromethane solution, the characteristics of which depend on donor ability of the alkynyl ligand substituents. Comparison of the emission wavelengths in 1-7 with those observed in the congeners based on the arom

U2 - 10.1016/j.jorganchem.2012.09.003

DO - 10.1016/j.jorganchem.2012.09.003

M3 - Article

SP - 65

EP - 71

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

SN - 0022-328X

ER -

ID: 7520127