Synthesis, characterization and morphotropic transitions in a family of M[(UO2)(CH3COO)3](H2O)n (M=Na, K, Rb, Cs; N=0-1.0) compounds

Standard

Synthesis, characterization and morphotropic transitions in a family of M[(UO₂)(CH₃COO)₃](H₂O)_n (M=Na, K, Rb, Cs; N=0-1.0) compounds. / Kornyakov, Ilya V.; Kalashnikova, Sophia A.; Gurzhiy, Vladislav V.; Britvin, Sergey N.; Belova, Elena V.; Krivovichev, Sergey V.

в: Zeitschrift fur Kristallographie - Crystalline Materials, Том 235, № 3, 01.03.2020, стр. 95-103.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

BibTeX

@article{74496738634548eba37347e089ade173,

title = "Synthesis, characterization and morphotropic transitions in a family of M[(UO2)(CH3COO)3](H2O)n (M=Na, K, Rb, Cs; N=0-1.0) compounds",

abstract = "Experimental investigations of crystallization in a family of uranyl triacetate compounds with Na, K, Rb and Cs were performed. The crystal structures of two novel Cs- and Rb-bearing tri(acetato)uranylates were solved, and the content of H 2O molecules in the crystal structure of K-bearing uranyl triacetate was refined. Synthesized compounds were analyzed using IR spectroscopy and single-crystal X-ray diffraction. Crystal chemical analysis of the M[(UO 2)(CH 3COO) 3](H 2O) n family (M = Na, K, Rb, Cs; n = 0-1.0) reveals the sequence of structural transformations depending on the size of alkali cation resulting in the symmetry reduction from cubic P?2 13 (for Na), through tetragonal I?4 1/a (for K and Rb) to triclinic P?1 space groups (for Cs), which is in accordance with the principle of morphotropism, suggested by Paul von Groth, founder of the Zeitschrift f{\"u}r Krystallographie journal, in 1870. ",

keywords = "acetate, cesium, crystal structure, IR spectroscopy, morphotropism, potassium, rubidium, sodium, uranium, X-ray diffraction",

author = "Kornyakov, {Ilya V.} and Kalashnikova, {Sophia A.} and Gurzhiy, {Vladislav V.} and Britvin, {Sergey N.} and Belova, {Elena V.} and Krivovichev, {Sergey V.}",

note = "Zeitschrift f{\"u}r Kristallographie - Crystalline Materials, Volume 235, Issue 3, Pages 95–103, eISSN 2196-7105, ISSN 2194-4946, DOI: https://doi.org/10.1515/zkri-2019-0070.",

year = "2020",

month = mar,

day = "1",

doi = "10.1515/zkri-2019-0070",

language = "English",

volume = "235",

pages = "95--103",

journal = "Zeitschrift fur Kristallographie - Crystalline Materials",

issn = "2194-4946",

publisher = "De Gruyter",

number = "3",

}

RIS

TY - JOUR

T1 - Synthesis, characterization and morphotropic transitions in a family of M[(UO2)(CH3COO)3](H2O)n (M=Na, K, Rb, Cs; N=0-1.0) compounds

AU - Kornyakov, Ilya V.

AU - Kalashnikova, Sophia A.

AU - Gurzhiy, Vladislav V.

AU - Britvin, Sergey N.

AU - Belova, Elena V.

AU - Krivovichev, Sergey V.

N1 - Zeitschrift für Kristallographie - Crystalline Materials, Volume 235, Issue 3, Pages 95–103, eISSN 2196-7105, ISSN 2194-4946, DOI: https://doi.org/10.1515/zkri-2019-0070.

PY - 2020/3/1

Y1 - 2020/3/1

N2 - Experimental investigations of crystallization in a family of uranyl triacetate compounds with Na, K, Rb and Cs were performed. The crystal structures of two novel Cs- and Rb-bearing tri(acetato)uranylates were solved, and the content of H 2O molecules in the crystal structure of K-bearing uranyl triacetate was refined. Synthesized compounds were analyzed using IR spectroscopy and single-crystal X-ray diffraction. Crystal chemical analysis of the M[(UO 2)(CH 3COO) 3](H 2O) n family (M = Na, K, Rb, Cs; n = 0-1.0) reveals the sequence of structural transformations depending on the size of alkali cation resulting in the symmetry reduction from cubic P?2 13 (for Na), through tetragonal I?4 1/a (for K and Rb) to triclinic P?1 space groups (for Cs), which is in accordance with the principle of morphotropism, suggested by Paul von Groth, founder of the Zeitschrift für Krystallographie journal, in 1870.

AB - Experimental investigations of crystallization in a family of uranyl triacetate compounds with Na, K, Rb and Cs were performed. The crystal structures of two novel Cs- and Rb-bearing tri(acetato)uranylates were solved, and the content of H 2O molecules in the crystal structure of K-bearing uranyl triacetate was refined. Synthesized compounds were analyzed using IR spectroscopy and single-crystal X-ray diffraction. Crystal chemical analysis of the M[(UO 2)(CH 3COO) 3](H 2O) n family (M = Na, K, Rb, Cs; n = 0-1.0) reveals the sequence of structural transformations depending on the size of alkali cation resulting in the symmetry reduction from cubic P?2 13 (for Na), through tetragonal I?4 1/a (for K and Rb) to triclinic P?1 space groups (for Cs), which is in accordance with the principle of morphotropism, suggested by Paul von Groth, founder of the Zeitschrift für Krystallographie journal, in 1870.

KW - acetate

KW - cesium

KW - crystal structure

KW - IR spectroscopy

KW - morphotropism

KW - potassium

KW - rubidium

KW - sodium

KW - uranium

KW - X-ray diffraction

UR - http://www.scopus.com/inward/record.url?scp=85081350095&partnerID=8YFLogxK

U2 - 10.1515/zkri-2019-0070

DO - 10.1515/zkri-2019-0070

M3 - Article

AN - SCOPUS:85081350095

VL - 235

SP - 95

EP - 103

JO - Zeitschrift fur Kristallographie - Crystalline Materials

JF - Zeitschrift fur Kristallographie - Crystalline Materials

SN - 2194-4946

IS - 3

ER -

ID: 52510864