Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Synthesis and structural characterization of new layered hydroselenites (enH2)[Ni(HSeO3)2Br2] and (dmedaH2)[Ni(HSeO3)2X2], X = Cl, Br. / Чаркин, Дмитрий Олегович; Гришаев, Василий Юрьевич; Сийдра, Олег Иоханнесович; Банару, Александр; Аксенов, Сергей Михайлович.
в: Structural Chemistry, Том 36, № 5, 01.10.2025, стр. 1779–1790.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Synthesis and structural characterization of new layered hydroselenites (enH2)[Ni(HSeO3)2Br2] and (dmedaH2)[Ni(HSeO3)2X2], X = Cl, Br.
AU - Чаркин, Дмитрий Олегович
AU - Гришаев, Василий Юрьевич
AU - Сийдра, Олег Иоханнесович
AU - Банару, Александр
AU - Аксенов, Сергей Михайлович
PY - 2025/10/1
Y1 - 2025/10/1
N2 - Three new nickel-based representatives of the so-called “layered hydroselenite” family have been characterized by single-crystal X-ray diffraction. In addition to the (enH2)[Ni(HSeO3)2Br2], the last missing member of the ethylenediammonium – transition metal hydroselenite-halide family, we were able to characterize the first members of a new family of compounds based on the N,N′-dimethylethylenediammonium cations, (dmedaH2)[Ni(HSeO3)2X2], X = Cl and Br. We compare the structural peculiarities of layered hydroselenites “stuffed” by the (enH2)2+ and (dmedaH2)2+ cations and predict existence of new series in this peculiar layered family.
AB - Three new nickel-based representatives of the so-called “layered hydroselenite” family have been characterized by single-crystal X-ray diffraction. In addition to the (enH2)[Ni(HSeO3)2Br2], the last missing member of the ethylenediammonium – transition metal hydroselenite-halide family, we were able to characterize the first members of a new family of compounds based on the N,N′-dimethylethylenediammonium cations, (dmedaH2)[Ni(HSeO3)2X2], X = Cl and Br. We compare the structural peculiarities of layered hydroselenites “stuffed” by the (enH2)2+ and (dmedaH2)2+ cations and predict existence of new series in this peculiar layered family.
KW - Inorganic synthesis
KW - Layered hydroselenites
KW - Nickel
KW - Selenium
UR - https://link.springer.com/article/10.1007/s11224-025-02477-8#citeas
UR - https://www.mendeley.com/catalogue/d66cb01e-67d3-34c0-8c0e-e9284ddf118c/
U2 - 10.1007/s11224-025-02477-8
DO - 10.1007/s11224-025-02477-8
M3 - Article
VL - 36
SP - 1779
EP - 1790
JO - Structural Chemistry
JF - Structural Chemistry
SN - 1040-0400
IS - 5
ER -
ID: 135630302