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Synthesis and structural characterization of new layered hydroselenites (enH2)[Ni(HSeO3)2Br2] and (dmedaH2)[Ni(HSeO3)2X2], X = Cl, Br. / Чаркин, Дмитрий Олегович; Гришаев, Василий Юрьевич; Сийдра, Олег Иоханнесович; Банару, Александр; Аксенов, Сергей Михайлович.

в: Structural Chemistry, Том 36, № 5, 01.10.2025, стр. 1779–1790.

Результаты исследований: Научные публикации в периодических изданияхстатьяРецензирование

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Author

Чаркин, Дмитрий Олегович ; Гришаев, Василий Юрьевич ; Сийдра, Олег Иоханнесович ; Банару, Александр ; Аксенов, Сергей Михайлович. / Synthesis and structural characterization of new layered hydroselenites (enH2)[Ni(HSeO3)2Br2] and (dmedaH2)[Ni(HSeO3)2X2], X = Cl, Br. в: Structural Chemistry. 2025 ; Том 36, № 5. стр. 1779–1790.

BibTeX

@article{8482adb7b56f486db4b267a09d70196b,
title = "Synthesis and structural characterization of new layered hydroselenites (enH2)[Ni(HSeO3)2Br2] and (dmedaH2)[Ni(HSeO3)2X2], X = Cl, Br.",
abstract = "Three new nickel-based representatives of the so-called “layered hydroselenite” family have been characterized by single-crystal X-ray diffraction. In addition to the (enH2)[Ni(HSeO3)2Br2], the last missing member of the ethylenediammonium – transition metal hydroselenite-halide family, we were able to characterize the first members of a new family of compounds based on the N,N′-dimethylethylenediammonium cations, (dmedaH2)[Ni(HSeO3)2X2], X = Cl and Br. We compare the structural peculiarities of layered hydroselenites “stuffed” by the (enH2)2+ and (dmedaH2)2+ cations and predict existence of new series in this peculiar layered family.",
keywords = "Inorganic synthesis, Layered hydroselenites, Nickel, Selenium",
author = "Чаркин, {Дмитрий Олегович} and Гришаев, {Василий Юрьевич} and Сийдра, {Олег Иоханнесович} and Александр Банару and Аксенов, {Сергей Михайлович}",
year = "2025",
month = oct,
day = "1",
doi = "10.1007/s11224-025-02477-8",
language = "English",
volume = "36",
pages = "1779–1790",
journal = "Structural Chemistry",
issn = "1040-0400",
publisher = "Springer Nature",
number = "5",

}

RIS

TY - JOUR

T1 - Synthesis and structural characterization of new layered hydroselenites (enH2)[Ni(HSeO3)2Br2] and (dmedaH2)[Ni(HSeO3)2X2], X = Cl, Br.

AU - Чаркин, Дмитрий Олегович

AU - Гришаев, Василий Юрьевич

AU - Сийдра, Олег Иоханнесович

AU - Банару, Александр

AU - Аксенов, Сергей Михайлович

PY - 2025/10/1

Y1 - 2025/10/1

N2 - Three new nickel-based representatives of the so-called “layered hydroselenite” family have been characterized by single-crystal X-ray diffraction. In addition to the (enH2)[Ni(HSeO3)2Br2], the last missing member of the ethylenediammonium – transition metal hydroselenite-halide family, we were able to characterize the first members of a new family of compounds based on the N,N′-dimethylethylenediammonium cations, (dmedaH2)[Ni(HSeO3)2X2], X = Cl and Br. We compare the structural peculiarities of layered hydroselenites “stuffed” by the (enH2)2+ and (dmedaH2)2+ cations and predict existence of new series in this peculiar layered family.

AB - Three new nickel-based representatives of the so-called “layered hydroselenite” family have been characterized by single-crystal X-ray diffraction. In addition to the (enH2)[Ni(HSeO3)2Br2], the last missing member of the ethylenediammonium – transition metal hydroselenite-halide family, we were able to characterize the first members of a new family of compounds based on the N,N′-dimethylethylenediammonium cations, (dmedaH2)[Ni(HSeO3)2X2], X = Cl and Br. We compare the structural peculiarities of layered hydroselenites “stuffed” by the (enH2)2+ and (dmedaH2)2+ cations and predict existence of new series in this peculiar layered family.

KW - Inorganic synthesis

KW - Layered hydroselenites

KW - Nickel

KW - Selenium

UR - https://link.springer.com/article/10.1007/s11224-025-02477-8#citeas

UR - https://www.mendeley.com/catalogue/d66cb01e-67d3-34c0-8c0e-e9284ddf118c/

U2 - 10.1007/s11224-025-02477-8

DO - 10.1007/s11224-025-02477-8

M3 - Article

VL - 36

SP - 1779

EP - 1790

JO - Structural Chemistry

JF - Structural Chemistry

SN - 1040-0400

IS - 5

ER -

ID: 135630302