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Synthesis and structural characterisation of the mixed metal clusters [Rh2Pt3(μ-CO)5(CO)4(PPh 3)3] and [Rh2Pt2(μ-CO)3-(CO)4(PPh 3)3]; crystal structure of [Rh2Pt3(μ-CO)5(CO)4(PPh 3)3]. / Dolgushin, Fiodor M.; Grachova, Elena V.; Heaton, Brian T.; Iggo, Jonathan A.; Koshevoy, Igor O.; Podkorytov, Ivan S.; Smawfield, Daniel J.; Tunik, Sergey P.; Whyman, Robin; Yanovskii, Aleksandr I.

в: Dalton Transactions, № 10, 21.05.1999, стр. 1609-1614.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

Harvard

Dolgushin, FM, Grachova, EV, Heaton, BT, Iggo, JA, Koshevoy, IO, Podkorytov, IS, Smawfield, DJ, Tunik, SP, Whyman, R & Yanovskii, AI 1999, 'Synthesis and structural characterisation of the mixed metal clusters [Rh2Pt3(μ-CO)5(CO)4(PPh 3)3] and [Rh2Pt2(μ-CO)3-(CO)4(PPh 3)3]; crystal structure of [Rh2Pt3(μ-CO)5(CO)4(PPh 3)3]', Dalton Transactions, № 10, стр. 1609-1614. https://doi.org/10.1039/a809118h, https://doi.org/10.1039/a809118h

APA

Dolgushin, F. M., Grachova, E. V., Heaton, B. T., Iggo, J. A., Koshevoy, I. O., Podkorytov, I. S., Smawfield, D. J., Tunik, S. P., Whyman, R., & Yanovskii, A. I. (1999). Synthesis and structural characterisation of the mixed metal clusters [Rh2Pt3(μ-CO)5(CO)4(PPh 3)3] and [Rh2Pt2(μ-CO)3-(CO)4(PPh 3)3]; crystal structure of [Rh2Pt3(μ-CO)5(CO)4(PPh 3)3]. Dalton Transactions, (10), 1609-1614. https://doi.org/10.1039/a809118h, https://doi.org/10.1039/a809118h

Vancouver

Dolgushin FM, Grachova EV, Heaton BT, Iggo JA, Koshevoy IO, Podkorytov IS и пр. Synthesis and structural characterisation of the mixed metal clusters [Rh2Pt3(μ-CO)5(CO)4(PPh 3)3] and [Rh2Pt2(μ-CO)3-(CO)4(PPh 3)3]; crystal structure of [Rh2Pt3(μ-CO)5(CO)4(PPh 3)3]. Dalton Transactions. 1999 Май 21;(10):1609-1614. https://doi.org/10.1039/a809118h, https://doi.org/10.1039/a809118h

Author

Dolgushin, Fiodor M. ; Grachova, Elena V. ; Heaton, Brian T. ; Iggo, Jonathan A. ; Koshevoy, Igor O. ; Podkorytov, Ivan S. ; Smawfield, Daniel J. ; Tunik, Sergey P. ; Whyman, Robin ; Yanovskii, Aleksandr I. / Synthesis and structural characterisation of the mixed metal clusters [Rh2Pt3(μ-CO)5(CO)4(PPh 3)3] and [Rh2Pt2(μ-CO)3-(CO)4(PPh 3)3]; crystal structure of [Rh2Pt3(μ-CO)5(CO)4(PPh 3)3]. в: Dalton Transactions. 1999 ; № 10. стр. 1609-1614.

BibTeX

@article{ca16aa2012424999ba353a880ec0b95a,
title = "Synthesis and structural characterisation of the mixed metal clusters [Rh2Pt3(μ-CO)5(CO)4(PPh 3)3] and [Rh2Pt2(μ-CO)3-(CO)4(PPh 3)3]; crystal structure of [Rh2Pt3(μ-CO)5(CO)4(PPh 3)3]",
abstract = "Two novel mixed metal rhodium-platinum clusters have been synthesized by the reaction of [Rh4(CO)12] with [Pt(PPh3)3]. The structure of [Rh2Pt3(μ-CO)5(CO)4(PPh 3)3] 1 has been established by a single crystal X-ray diffraction study. The tetranuclear cluster [Rh2Pt2(μ-CO)3(CO)4(PPh 3)3] 2 has been characterised by FAB mass spectrometry and shown by various multinuclear NMR techniques (13C, 31P, {31P-31P} COSY and {13C-103Rh} and {31P-103Rh} heteronuclear multiple quantum coherence, HMQC) to adopt a butterfly type structure. The carbonyl migration pathways in 2 have been established by a combination of EXSY and 1-D variable temperature measurements; independent localised exchange about the hinge rhodium atoms and interchange of bridging and semi-bridging carbonyls on the Pt-Rh bonds occur.",
author = "Dolgushin, {Fiodor M.} and Grachova, {Elena V.} and Heaton, {Brian T.} and Iggo, {Jonathan A.} and Koshevoy, {Igor O.} and Podkorytov, {Ivan S.} and Smawfield, {Daniel J.} and Tunik, {Sergey P.} and Robin Whyman and Yanovskii, {Aleksandr I.}",
year = "1999",
month = may,
day = "21",
doi = "10.1039/a809118h",
language = "English",
pages = "1609--1614",
journal = "Dalton Transactions",
issn = "1477-9226",
publisher = "Royal Society of Chemistry",
number = "10",

}

RIS

TY - JOUR

T1 - Synthesis and structural characterisation of the mixed metal clusters [Rh2Pt3(μ-CO)5(CO)4(PPh 3)3] and [Rh2Pt2(μ-CO)3-(CO)4(PPh 3)3]; crystal structure of [Rh2Pt3(μ-CO)5(CO)4(PPh 3)3]

AU - Dolgushin, Fiodor M.

AU - Grachova, Elena V.

AU - Heaton, Brian T.

AU - Iggo, Jonathan A.

AU - Koshevoy, Igor O.

AU - Podkorytov, Ivan S.

AU - Smawfield, Daniel J.

AU - Tunik, Sergey P.

AU - Whyman, Robin

AU - Yanovskii, Aleksandr I.

PY - 1999/5/21

Y1 - 1999/5/21

N2 - Two novel mixed metal rhodium-platinum clusters have been synthesized by the reaction of [Rh4(CO)12] with [Pt(PPh3)3]. The structure of [Rh2Pt3(μ-CO)5(CO)4(PPh 3)3] 1 has been established by a single crystal X-ray diffraction study. The tetranuclear cluster [Rh2Pt2(μ-CO)3(CO)4(PPh 3)3] 2 has been characterised by FAB mass spectrometry and shown by various multinuclear NMR techniques (13C, 31P, {31P-31P} COSY and {13C-103Rh} and {31P-103Rh} heteronuclear multiple quantum coherence, HMQC) to adopt a butterfly type structure. The carbonyl migration pathways in 2 have been established by a combination of EXSY and 1-D variable temperature measurements; independent localised exchange about the hinge rhodium atoms and interchange of bridging and semi-bridging carbonyls on the Pt-Rh bonds occur.

AB - Two novel mixed metal rhodium-platinum clusters have been synthesized by the reaction of [Rh4(CO)12] with [Pt(PPh3)3]. The structure of [Rh2Pt3(μ-CO)5(CO)4(PPh 3)3] 1 has been established by a single crystal X-ray diffraction study. The tetranuclear cluster [Rh2Pt2(μ-CO)3(CO)4(PPh 3)3] 2 has been characterised by FAB mass spectrometry and shown by various multinuclear NMR techniques (13C, 31P, {31P-31P} COSY and {13C-103Rh} and {31P-103Rh} heteronuclear multiple quantum coherence, HMQC) to adopt a butterfly type structure. The carbonyl migration pathways in 2 have been established by a combination of EXSY and 1-D variable temperature measurements; independent localised exchange about the hinge rhodium atoms and interchange of bridging and semi-bridging carbonyls on the Pt-Rh bonds occur.

UR - http://www.scopus.com/inward/record.url?scp=33748646012&partnerID=8YFLogxK

U2 - 10.1039/a809118h

DO - 10.1039/a809118h

M3 - Article

SP - 1609

EP - 1614

JO - Dalton Transactions

JF - Dalton Transactions

SN - 1477-9226

IS - 10

ER -

ID: 5115390