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Synthesis and extractive properties of hexaphosphorylated calix[6]arenes. / Rudzevich, Yu I.; Drapailo, A. B.; Rudzevich, V. L.; Miroshnichenko, V. I.; Kal'chenko, V. I.; Smirnov, I. V.; Babain, V. A.; Varnek, A. A.; Wipff, G.

в: Russian Journal of General Chemistry, Том 72, № 11, 01.01.2002, стр. 1736-1742.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

Harvard

Rudzevich, YI, Drapailo, AB, Rudzevich, VL, Miroshnichenko, VI, Kal'chenko, VI, Smirnov, IV, Babain, VA, Varnek, AA & Wipff, G 2002, 'Synthesis and extractive properties of hexaphosphorylated calix[6]arenes', Russian Journal of General Chemistry, Том. 72, № 11, стр. 1736-1742. https://doi.org/10.1023/A:1023389128977

APA

Rudzevich, Y. I., Drapailo, A. B., Rudzevich, V. L., Miroshnichenko, V. I., Kal'chenko, V. I., Smirnov, I. V., Babain, V. A., Varnek, A. A., & Wipff, G. (2002). Synthesis and extractive properties of hexaphosphorylated calix[6]arenes. Russian Journal of General Chemistry, 72(11), 1736-1742. https://doi.org/10.1023/A:1023389128977

Vancouver

Rudzevich YI, Drapailo AB, Rudzevich VL, Miroshnichenko VI, Kal'chenko VI, Smirnov IV и пр. Synthesis and extractive properties of hexaphosphorylated calix[6]arenes. Russian Journal of General Chemistry. 2002 Янв. 1;72(11):1736-1742. https://doi.org/10.1023/A:1023389128977

Author

Rudzevich, Yu I. ; Drapailo, A. B. ; Rudzevich, V. L. ; Miroshnichenko, V. I. ; Kal'chenko, V. I. ; Smirnov, I. V. ; Babain, V. A. ; Varnek, A. A. ; Wipff, G. / Synthesis and extractive properties of hexaphosphorylated calix[6]arenes. в: Russian Journal of General Chemistry. 2002 ; Том 72, № 11. стр. 1736-1742.

BibTeX

@article{bd9f2116d1874946a88a29672fda1eda,
title = "Synthesis and extractive properties of hexaphosphorylated calix[6]arenes",
abstract = "A series of calix[6]arenes substituted with phosphoryl functional groups were prepared by the Arbuzov reaction of hexakis(chloromethyl)calix[6]arene hexamethyl ether with isopropyl esters of trivalent phosphorus acids, followed by appropriate chemical transformations. Molecular modeling and NMR data show that phosphorylated calix[6]arenes exist in the stereochemically labile 1,2-alternate conformation. The extractive power of these compounds with respect to americium and europium was studied. Due to the cooperative binding of the metal cation with phosphoryl groups, the phosphorylated calixarenes are more effective extractants than their acylcic analogs and commercial organophosphorus extractants.",
author = "Rudzevich, {Yu I.} and Drapailo, {A. B.} and Rudzevich, {V. L.} and Miroshnichenko, {V. I.} and Kal'chenko, {V. I.} and Smirnov, {I. V.} and Babain, {V. A.} and Varnek, {A. A.} and G. Wipff",
year = "2002",
month = jan,
day = "1",
doi = "10.1023/A:1023389128977",
language = "English",
volume = "72",
pages = "1736--1742",
journal = "Russian Journal of General Chemistry",
issn = "1070-3632",
publisher = "МАИК {"}Наука/Интерпериодика{"}",
number = "11",

}

RIS

TY - JOUR

T1 - Synthesis and extractive properties of hexaphosphorylated calix[6]arenes

AU - Rudzevich, Yu I.

AU - Drapailo, A. B.

AU - Rudzevich, V. L.

AU - Miroshnichenko, V. I.

AU - Kal'chenko, V. I.

AU - Smirnov, I. V.

AU - Babain, V. A.

AU - Varnek, A. A.

AU - Wipff, G.

PY - 2002/1/1

Y1 - 2002/1/1

N2 - A series of calix[6]arenes substituted with phosphoryl functional groups were prepared by the Arbuzov reaction of hexakis(chloromethyl)calix[6]arene hexamethyl ether with isopropyl esters of trivalent phosphorus acids, followed by appropriate chemical transformations. Molecular modeling and NMR data show that phosphorylated calix[6]arenes exist in the stereochemically labile 1,2-alternate conformation. The extractive power of these compounds with respect to americium and europium was studied. Due to the cooperative binding of the metal cation with phosphoryl groups, the phosphorylated calixarenes are more effective extractants than their acylcic analogs and commercial organophosphorus extractants.

AB - A series of calix[6]arenes substituted with phosphoryl functional groups were prepared by the Arbuzov reaction of hexakis(chloromethyl)calix[6]arene hexamethyl ether with isopropyl esters of trivalent phosphorus acids, followed by appropriate chemical transformations. Molecular modeling and NMR data show that phosphorylated calix[6]arenes exist in the stereochemically labile 1,2-alternate conformation. The extractive power of these compounds with respect to americium and europium was studied. Due to the cooperative binding of the metal cation with phosphoryl groups, the phosphorylated calixarenes are more effective extractants than their acylcic analogs and commercial organophosphorus extractants.

UR - http://www.scopus.com/inward/record.url?scp=0036989737&partnerID=8YFLogxK

U2 - 10.1023/A:1023389128977

DO - 10.1023/A:1023389128977

M3 - Article

AN - SCOPUS:0036989737

VL - 72

SP - 1736

EP - 1742

JO - Russian Journal of General Chemistry

JF - Russian Journal of General Chemistry

SN - 1070-3632

IS - 11

ER -

ID: 53581557