Synthesis and Electrochemical Properties of Composite Films Based on Poly-3,4-ethylenedioxythiophene with Inclusions of Silver Particles

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Synthesis and Electrochemical Properties of Composite Films Based on Poly-3,4-ethylenedioxythiophene with Inclusions of Silver Particles. / Tolstopyatova, E.G.; Pogulyaichenko, N.A.; Kondratiev, V.V.

в: Russian Journal of Electrochemistry, Том 50, № 6, 2014, стр. 510-516.

Результаты исследований: Научные публикации в периодических изданиях › статья

BibTeX

@article{60b251f1bdf04e53b5b5d428fbde5243,

title = "Synthesis and Electrochemical Properties of Composite Films Based on Poly-3,4-ethylenedioxythiophene with Inclusions of Silver Particles",

abstract = "The electrochemical behavior of PEDOT/Ag composite films obtained by chemical deposition of ultrafine Ag particles into the poly-3,4-thylenedioxythiophene (PEDOT) matrix was studied. The film morphology was characterized by transmission electron microscopy (TEM). The changes in the mass of the films during the chemical deposition of silver into the polymer structure were evaluated microgravimetrically. The mass of the included metallic silver particles depends on the synthesis time and the initial concentration of silver ions in solution. The cyclic voltammograms (CVs) of PEDOT/Ag films in sodium nitrate solutions and sodium nitrate solutions with additions of chloride ions were studied. The cyclic voltammograms of PEDOT/Ag films in chloride-containing solutions showed the peaks of the oxidation of silver and reduction of the oxidation product, which were absent on the CVs of the starting PEDOT film.",

keywords = "composite materials, poly-3, 4-ethylenedioxythiophene, silver particles, conducting polymers, cyclic voltammetry, quartz microbalance",

author = "E.G. Tolstopyatova and N.A. Pogulyaichenko and V.V. Kondratiev",

year = "2014",

doi = "10.1134/S1023193514060111",

language = "English",

volume = "50",

pages = "510--516",

journal = "Russian Journal of Electrochemistry",

issn = "1023-1935",

publisher = "МАИК {"}Наука/Интерпериодика{"}",

number = "6",

}

RIS

TY - JOUR

T1 - Synthesis and Electrochemical Properties of Composite Films Based on Poly-3,4-ethylenedioxythiophene with Inclusions of Silver Particles

AU - Tolstopyatova, E.G.

AU - Pogulyaichenko, N.A.

AU - Kondratiev, V.V.

PY - 2014

Y1 - 2014

N2 - The electrochemical behavior of PEDOT/Ag composite films obtained by chemical deposition of ultrafine Ag particles into the poly-3,4-thylenedioxythiophene (PEDOT) matrix was studied. The film morphology was characterized by transmission electron microscopy (TEM). The changes in the mass of the films during the chemical deposition of silver into the polymer structure were evaluated microgravimetrically. The mass of the included metallic silver particles depends on the synthesis time and the initial concentration of silver ions in solution. The cyclic voltammograms (CVs) of PEDOT/Ag films in sodium nitrate solutions and sodium nitrate solutions with additions of chloride ions were studied. The cyclic voltammograms of PEDOT/Ag films in chloride-containing solutions showed the peaks of the oxidation of silver and reduction of the oxidation product, which were absent on the CVs of the starting PEDOT film.

AB - The electrochemical behavior of PEDOT/Ag composite films obtained by chemical deposition of ultrafine Ag particles into the poly-3,4-thylenedioxythiophene (PEDOT) matrix was studied. The film morphology was characterized by transmission electron microscopy (TEM). The changes in the mass of the films during the chemical deposition of silver into the polymer structure were evaluated microgravimetrically. The mass of the included metallic silver particles depends on the synthesis time and the initial concentration of silver ions in solution. The cyclic voltammograms (CVs) of PEDOT/Ag films in sodium nitrate solutions and sodium nitrate solutions with additions of chloride ions were studied. The cyclic voltammograms of PEDOT/Ag films in chloride-containing solutions showed the peaks of the oxidation of silver and reduction of the oxidation product, which were absent on the CVs of the starting PEDOT film.

KW - composite materials

KW - poly-3

KW - 4-ethylenedioxythiophene

KW - silver particles

KW - conducting polymers

KW - cyclic voltammetry

KW - quartz microbalance

U2 - 10.1134/S1023193514060111

DO - 10.1134/S1023193514060111

M3 - Article

VL - 50

SP - 510

EP - 516

JO - Russian Journal of Electrochemistry

JF - Russian Journal of Electrochemistry

SN - 1023-1935

IS - 6

ER -

ID: 7017911