Synthesis and crystal structure of new hydrated lead selenite nitrate Pb4(SeO3)3(NO3)2⋅2H2O

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Synthesis and crystal structure of new hydrated lead selenite nitrate Pb4(SeO3)3(NO3)2⋅2H2O. / Сийдра, Олег Иоханнесович ; Гришаев, Василий Юрьевич.

в: Journal of Structural Chemistry, Том 65, № 7, 01.08.2024, стр. 1432-1438.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

BibTeX

@article{7138e620be6a4081bdf10969233f4d74,

title = "Synthesis and crystal structure of new hydrated lead selenite nitrate Pb4(SeO3)3(NO3)2⋅2H2O",

abstract = "Abstract: The synthesis and crystal structure of new hydrated lead selenite nitrate Pb4(SeO3)3(NO3)2·2H2O (1) are reported. The crystal structure of 1 (, a = 7.2590(2) {\AA}, b = 7.6454(2) {\AA}, c = 14.7293(4) {\AA}, α = 84.386(2)°, β = 78.311(2)°, γ = 83.643(2)°, V = 793.18(4) {\AA}3, R1 = 3.1%) belongs to a new structure type. It is based on a porous framework composed of [Pb4(SeO3)3]2+ layers strongly bound via nitrate anions. Water molecules are located in the channels. Stereochemically active electron pairs of SeO3E groups are directed toward each other. The structure of 1 is compared with similar architectures involving Pb2+ and Se4+ cations.",

keywords = "inorganic synthesis, lead, nitrates, selenites",

author = "Сийдра, {Олег Иоханнесович} and Гришаев, {Василий Юрьевич}",

year = "2024",

month = aug,

day = "1",

doi = "10.1134/s002247662407014x",

language = "English",

volume = "65",

pages = "1432--1438",

journal = "Journal of Structural Chemistry",

issn = "0022-4766",

publisher = "Springer Nature",

number = "7",

}

RIS

TY - JOUR

T1 - Synthesis and crystal structure of new hydrated lead selenite nitrate Pb4(SeO3)3(NO3)2⋅2H2O

AU - Сийдра, Олег Иоханнесович

AU - Гришаев, Василий Юрьевич

PY - 2024/8/1

Y1 - 2024/8/1

N2 - Abstract: The synthesis and crystal structure of new hydrated lead selenite nitrate Pb4(SeO3)3(NO3)2·2H2O (1) are reported. The crystal structure of 1 (, a = 7.2590(2) Å, b = 7.6454(2) Å, c = 14.7293(4) Å, α = 84.386(2)°, β = 78.311(2)°, γ = 83.643(2)°, V = 793.18(4) Å3, R1 = 3.1%) belongs to a new structure type. It is based on a porous framework composed of [Pb4(SeO3)3]2+ layers strongly bound via nitrate anions. Water molecules are located in the channels. Stereochemically active electron pairs of SeO3E groups are directed toward each other. The structure of 1 is compared with similar architectures involving Pb2+ and Se4+ cations.

AB - Abstract: The synthesis and crystal structure of new hydrated lead selenite nitrate Pb4(SeO3)3(NO3)2·2H2O (1) are reported. The crystal structure of 1 (, a = 7.2590(2) Å, b = 7.6454(2) Å, c = 14.7293(4) Å, α = 84.386(2)°, β = 78.311(2)°, γ = 83.643(2)°, V = 793.18(4) Å3, R1 = 3.1%) belongs to a new structure type. It is based on a porous framework composed of [Pb4(SeO3)3]2+ layers strongly bound via nitrate anions. Water molecules are located in the channels. Stereochemically active electron pairs of SeO3E groups are directed toward each other. The structure of 1 is compared with similar architectures involving Pb2+ and Se4+ cations.

KW - inorganic synthesis

KW - lead

KW - nitrates

KW - selenites

UR - https://link.springer.com/article/10.1134/S002247662407014X

UR - https://www.mendeley.com/catalogue/4a6c6cbd-360d-37b3-85bd-8187a7e157c6/

U2 - 10.1134/s002247662407014x

DO - 10.1134/s002247662407014x

M3 - Article

VL - 65

SP - 1432

EP - 1438

JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

SN - 0022-4766

IS - 7

ER -

ID: 122276627