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Synthesis and crystal structure of 2-isocyano-4-methylphenyl diphenylacetate: A rare case of an easily accessible odourless isocyanide. / Boyarskaya, D.; Avdontceva, M.; Chulkova, T.

в: Acta Crystallographica Section C: Crystal Structure Communications, Том 71, № 2, 2015, стр. 155-158.

Результаты исследований: Научные публикации в периодических изданиях › статья

Harvard

Boyarskaya, D, Avdontceva, M & Chulkova, T 2015, 'Synthesis and crystal structure of 2-isocyano-4-methylphenyl diphenylacetate: A rare case of an easily accessible odourless isocyanide', Acta Crystallographica Section C: Crystal Structure Communications, Том. 71, № 2, стр. 155-158. https://doi.org/10.1107/S2053229615001588

APA

Boyarskaya, D., Avdontceva, M., & Chulkova, T. (2015). Synthesis and crystal structure of 2-isocyano-4-methylphenyl diphenylacetate: A rare case of an easily accessible odourless isocyanide. Acta Crystallographica Section C: Crystal Structure Communications, 71(2), 155-158. https://doi.org/10.1107/S2053229615001588

Vancouver

Boyarskaya D, Avdontceva M, Chulkova T. Synthesis and crystal structure of 2-isocyano-4-methylphenyl diphenylacetate: A rare case of an easily accessible odourless isocyanide. Acta Crystallographica Section C: Crystal Structure Communications. 2015;71(2):155-158. https://doi.org/10.1107/S2053229615001588

Author

Boyarskaya, D. ; Avdontceva, M. ; Chulkova, T. / Synthesis and crystal structure of 2-isocyano-4-methylphenyl diphenylacetate: A rare case of an easily accessible odourless isocyanide. в: Acta Crystallographica Section C: Crystal Structure Communications. 2015 ; Том 71, № 2. стр. 155-158.

BibTeX

@article{585fba478fb94fa491b3547bcc21bd97,
title = "Synthesis and crystal structure of 2-isocyano-4-methylphenyl diphenylacetate: A rare case of an easily accessible odourless isocyanide",
abstract = "Acidic hydrogen containing 2-isocyano-4-methylphenyl diphenylacetate, C22H17NO2, (I), was synthesized by the base-promoted reaction between 5-methylbenzoxazole and diphenylacetyl chloride. Achiral (I) crystallizes in the chiral P212121 space group. The C N bond length is 1.164(2){\AA} and the angle between the OCO and 2-isocyano-4-methylphenyl planes is 69.10(16)°. Molecules are linked via C=O⋯Hphenyl and bifurcated N C⋯Hphenyl/N C⋯Hmethine hydrogen bonds, forming one-dimensional arrays.",
author = "D. Boyarskaya and M. Avdontceva and T. Chulkova",
year = "2015",
doi = "10.1107/S2053229615001588",
language = "English",
volume = "71",
pages = "155--158",
journal = "Acta Crystallographica Section C-Structural Chemistry",
issn = "2053-2296",
publisher = "International Union of Crystallography",
number = "2",

}

RIS

TY - JOUR

T1 - Synthesis and crystal structure of 2-isocyano-4-methylphenyl diphenylacetate: A rare case of an easily accessible odourless isocyanide

AU - Boyarskaya, D.

AU - Avdontceva, M.

AU - Chulkova, T.

PY - 2015

Y1 - 2015

N2 - Acidic hydrogen containing 2-isocyano-4-methylphenyl diphenylacetate, C22H17NO2, (I), was synthesized by the base-promoted reaction between 5-methylbenzoxazole and diphenylacetyl chloride. Achiral (I) crystallizes in the chiral P212121 space group. The C N bond length is 1.164(2)Å and the angle between the OCO and 2-isocyano-4-methylphenyl planes is 69.10(16)°. Molecules are linked via C=O⋯Hphenyl and bifurcated N C⋯Hphenyl/N C⋯Hmethine hydrogen bonds, forming one-dimensional arrays.

AB - Acidic hydrogen containing 2-isocyano-4-methylphenyl diphenylacetate, C22H17NO2, (I), was synthesized by the base-promoted reaction between 5-methylbenzoxazole and diphenylacetyl chloride. Achiral (I) crystallizes in the chiral P212121 space group. The C N bond length is 1.164(2)Å and the angle between the OCO and 2-isocyano-4-methylphenyl planes is 69.10(16)°. Molecules are linked via C=O⋯Hphenyl and bifurcated N C⋯Hphenyl/N C⋯Hmethine hydrogen bonds, forming one-dimensional arrays.

U2 - 10.1107/S2053229615001588

DO - 10.1107/S2053229615001588

M3 - Article

VL - 71

SP - 155

EP - 158

JO - Acta Crystallographica Section C-Structural Chemistry

JF - Acta Crystallographica Section C-Structural Chemistry

SN - 2053-2296

IS - 2

ER -

ID: 3928734