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Synthesis and Characterization of (Ca,Sr)[C2O4]nH2O Solid Solutions: Variations of Phase Composition, Crystal Morphologies and in Ionic Substitutions. / Rusakov , Aleksei V.; Kuzmina, Mariya A. ; Izatulina, Alina R.; Frank-Kamenetskaya, Olga V. .
в: Crystals, Том 9, № 12, 654, 06.12.2019.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Synthesis and Characterization of (Ca,Sr)[C2O4]nH2O Solid Solutions: Variations of Phase Composition, Crystal Morphologies and in Ionic Substitutions
AU - Rusakov , Aleksei V.
AU - Kuzmina, Mariya A.
AU - Izatulina, Alina R.
AU - Frank-Kamenetskaya, Olga V.
N1 - Rusakov, A.V.; Kuzmina, M.A.; Izatulina, A.R.; Frank-Kamenetskaya, O.V. Synthesis and Characterization of (Ca,Sr)[C2O4]∙nH2O Solid Solutions: Variations of Phase Composition, Crystal Morphologies and in Ionic Substitutions. Crystals 2019, 9, 654.
PY - 2019/12/6
Y1 - 2019/12/6
N2 - To study strontium (Sr) incorporation into calcium oxalates (weddellite and whewellite), calcium-strontium oxalate solid solutions (Ca,Sr)[C2O4]nH2O (n = 1, 2) are synthesized and studied by a complex of methods: powder X-ray diraction (PXRD), scanning electron microscopy (SEM) and energy dispersive X-ray (EDX) spectroscopy. Two series of solid solutions,isomorphous (Ca,Sr)[C2O4](2.5 - x)H2O) (space group I4/m) and isodimorphous Ca[C2O4]H2O(sp.gr.P21/c)–Sr[C2O4]H2O(sp.gr. P 1), are experimentally detected. The morphogenetic regularities of their crystallization are revealed. The factors controlling this process are discussed.
AB - To study strontium (Sr) incorporation into calcium oxalates (weddellite and whewellite), calcium-strontium oxalate solid solutions (Ca,Sr)[C2O4]nH2O (n = 1, 2) are synthesized and studied by a complex of methods: powder X-ray diraction (PXRD), scanning electron microscopy (SEM) and energy dispersive X-ray (EDX) spectroscopy. Two series of solid solutions,isomorphous (Ca,Sr)[C2O4](2.5 - x)H2O) (space group I4/m) and isodimorphous Ca[C2O4]H2O(sp.gr.P21/c)–Sr[C2O4]H2O(sp.gr. P 1), are experimentally detected. The morphogenetic regularities of their crystallization are revealed. The factors controlling this process are discussed.
KW - Calcium oxalate
KW - strontium oxalate
KW - Solid solutions
KW - ionic substitutions
KW - Weddellite
KW - Whewellite
KW - X-Ray powder diffraction
KW - scanning electron microscopy
KW - EDX spectroscopy
UR - https://www.mdpi.com/2073-4352/9/12/654
UR - https://www.researchgate.net/publication/337836027_Synthesis_and_Characterization_of_CaSrC2O4nH2O_Solid_Solutions_Variations_of_Phase_Composition_Crystal_Morphologies_and_in_Ionic_Substitutions
M3 - Article
VL - 9
JO - Liquid Crystals Today
JF - Liquid Crystals Today
SN - 1358-314X
IS - 12
M1 - 654
ER -
ID: 49823482