Synthesis and Analytical Characteristics of New Membrane Materials for Thallium(I) Selective Sensors

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Synthesis and Analytical Characteristics of New Membrane Materials for Thallium(I) Selective Sensors. / Kalyagin, D. S.; Smirnov, I. V.; Karavan, M. D.; Eremin, V. V.; Verkhovskaya, E. A.; Kalinin, E. O.; Ermolenko, Yu E.

в: Russian Journal of Applied Chemistry, Том 94, № 9, 09.2021, стр. 1222-1225.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

BibTeX

@article{769a4726648f4ac1b3304bcf28282eec,

title = "Synthesis and Analytical Characteristics of New Membrane Materials for Thallium(I) Selective Sensors",

abstract = "Abstract: The most optimal membrane samples were synthesized, tested, and selected and a comprehensive study of the transport and analytical parameters of membrane materials for potentiometric sensors based on chalcogenide glasses in the TlI–Ag2Se–As2Se3 system was conducted. Thallium-selective sensor samples with membranes of the composition: 20 mol % TlI–30 mol % Ag2Se–50 mol % As2Se3 and 25 mol % TlI–25 mol % Ag2Se–50 mol % As2Se3, demonstrated the best parameters of the electrode function (57–58 mV/pTl), a detection limit of 3 × 10–6 M, and the best characteristics of selectivity with respect to a number of heavy metal cations.",

keywords = "detection limit, electrochemical cell, express method, potentiometric determination, selectivity, thallium ion sensors",

author = "Kalyagin, {D. S.} and Smirnov, {I. V.} and Karavan, {M. D.} and Eremin, {V. V.} and Verkhovskaya, {E. A.} and Kalinin, {E. O.} and Ermolenko, {Yu E.}",

note = "Publisher Copyright: {\textcopyright} 2021, Pleiades Publishing, Ltd.",

year = "2021",

month = sep,

doi = "10.1134/S1070427221090044",

language = "English",

volume = "94",

pages = "1222--1225",

journal = "Russian Journal of Applied Chemistry",

issn = "1070-4272",

publisher = "МАИК {"}Наука/Интерпериодика{"}",

number = "9",

}

RIS

TY - JOUR

T1 - Synthesis and Analytical Characteristics of New Membrane Materials for Thallium(I) Selective Sensors

AU - Kalyagin, D. S.

AU - Smirnov, I. V.

AU - Karavan, M. D.

AU - Eremin, V. V.

AU - Verkhovskaya, E. A.

AU - Kalinin, E. O.

AU - Ermolenko, Yu E.

PY - 2021/9

Y1 - 2021/9

N2 - Abstract: The most optimal membrane samples were synthesized, tested, and selected and a comprehensive study of the transport and analytical parameters of membrane materials for potentiometric sensors based on chalcogenide glasses in the TlI–Ag2Se–As2Se3 system was conducted. Thallium-selective sensor samples with membranes of the composition: 20 mol % TlI–30 mol % Ag2Se–50 mol % As2Se3 and 25 mol % TlI–25 mol % Ag2Se–50 mol % As2Se3, demonstrated the best parameters of the electrode function (57–58 mV/pTl), a detection limit of 3 × 10–6 M, and the best characteristics of selectivity with respect to a number of heavy metal cations.

AB - Abstract: The most optimal membrane samples were synthesized, tested, and selected and a comprehensive study of the transport and analytical parameters of membrane materials for potentiometric sensors based on chalcogenide glasses in the TlI–Ag2Se–As2Se3 system was conducted. Thallium-selective sensor samples with membranes of the composition: 20 mol % TlI–30 mol % Ag2Se–50 mol % As2Se3 and 25 mol % TlI–25 mol % Ag2Se–50 mol % As2Se3, demonstrated the best parameters of the electrode function (57–58 mV/pTl), a detection limit of 3 × 10–6 M, and the best characteristics of selectivity with respect to a number of heavy metal cations.

KW - detection limit

KW - electrochemical cell

KW - express method

KW - potentiometric determination

KW - selectivity

KW - thallium ion sensors

UR - http://www.scopus.com/inward/record.url?scp=85121752063&partnerID=8YFLogxK

U2 - 10.1134/S1070427221090044

DO - 10.1134/S1070427221090044

M3 - Article

AN - SCOPUS:85121752063

VL - 94

SP - 1222

EP - 1225

JO - Russian Journal of Applied Chemistry

JF - Russian Journal of Applied Chemistry

SN - 1070-4272

IS - 9

ER -

ID: 92448397