Synchronization of fractional-order hyperchaotic complex systems is an interesting phenomenon since it has several applications in applied sciences. Based on the complexity of hyperchaotic dynamical systems and unpredictability of hidden attractors, which may exist in their phase spaces and could be beneficial in secure communications, a scheme to derive the analytical formula of the control functions is stated to study active control synchronization. Further comparison of this analytical formula with numerical experiments yields an interesting agreement. A novel fractional-order complex Sprott system is proposed to study this kind of synchronization and its dynamics. A secure communication scheme based on the active control synchronization of hyperchaotic fractional-order complex Sprott system is presented. Two types of masked messages (plain text and audio signal) are considered as test examples.