Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Symmetry of solvation sheaths of monatomic ions according to NMR relaxation data. / Chizhik, V. I.; Podkorytov, I. S.; Kaikkonen, A. P.
в: Russian Journal of Physical Chemistry A, Том 70, № 3, 01.03.1996, стр. 416-420.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Symmetry of solvation sheaths of monatomic ions according to NMR relaxation data
AU - Chizhik, V. I.
AU - Podkorytov, I. S.
AU - Kaikkonen, A. P.
PY - 1996/3/1
Y1 - 1996/3/1
N2 - The rates of spin-lattice relaxation of the nuclei of 7Li, 23Na, 71Ga, and 139La ions in solutions of electrolytes are studied as functions of the concentration of a deuterated analog of solvent. An ultrahigh sensitivity of quadrupole relaxation to the symmetry of solvation sheaths of monatomic ions is shown. The data on the ion nuclei relaxation are compared to the results of investigation of the 2H and 17O nuclei of the solvent, as well as the 14N nuclei of nitrate anions. A semiquantitative description of the effects studied is given.
AB - The rates of spin-lattice relaxation of the nuclei of 7Li, 23Na, 71Ga, and 139La ions in solutions of electrolytes are studied as functions of the concentration of a deuterated analog of solvent. An ultrahigh sensitivity of quadrupole relaxation to the symmetry of solvation sheaths of monatomic ions is shown. The data on the ion nuclei relaxation are compared to the results of investigation of the 2H and 17O nuclei of the solvent, as well as the 14N nuclei of nitrate anions. A semiquantitative description of the effects studied is given.
UR - http://www.scopus.com/inward/record.url?scp=0030541792&partnerID=8YFLogxK
M3 - Article
AN - SCOPUS:0030541792
VL - 70
SP - 416
EP - 420
JO - Russian Journal of Physical Chemistry A
JF - Russian Journal of Physical Chemistry A
SN - 0036-0244
IS - 3
ER -
ID: 37037623