Standard

Swelling behavior and network characterization of hydrogels from linear polyacrylamide crosslinked with glutaraldehyde. / Dmitriev, Ivan; Kuryndin, Ivan; Bobrova, Natalya; Smirnov, Michael.

в: Materials Today Communications, Том 4, 01.09.2015, стр. 93-100.

Результаты исследований: Научные публикации в периодических изданияхстатьяРецензирование

Harvard

APA

Vancouver

Author

Dmitriev, Ivan ; Kuryndin, Ivan ; Bobrova, Natalya ; Smirnov, Michael. / Swelling behavior and network characterization of hydrogels from linear polyacrylamide crosslinked with glutaraldehyde. в: Materials Today Communications. 2015 ; Том 4. стр. 93-100.

BibTeX

@article{f95b85599db84351933040043f31d287,
title = "Swelling behavior and network characterization of hydrogels from linear polyacrylamide crosslinked with glutaraldehyde",
abstract = "Polyacrylamide hydrogels have been prepared by crosslinking reaction between linear polyacrylamide (PAAm) and glutaraldehyde (GA) in acidic medium. The equilibrium swelling degree, modulus of elasticity and structure parameters of the network have been investigated as functions of the initial polymer concentration and the crosslinker content. Stability of GA crosslinks between PAAm chains has been demonstrated under the acid and basic conditions. It has been suggested that the crosslinking reaction can be presented as two stage process, which distinguishes different accessibility of aldehyde and amide groups for cross-linking agent in conditions of macromolecule distancing. The method provides formation of PAAm hydrogels with the values of the swelling degree and mechanical characteristics, which are close to the hydrogels prepared by traditional method of free radical crosslinking copolymerization.",
author = "Ivan Dmitriev and Ivan Kuryndin and Natalya Bobrova and Michael Smirnov",
note = "Publisher Copyright: {\textcopyright} 2015.",
year = "2015",
month = sep,
day = "1",
doi = "10.1016/j.mtcomm.2015.06.005",
language = "English",
volume = "4",
pages = "93--100",
journal = "Materials Today Communications",
issn = "2352-4928",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Swelling behavior and network characterization of hydrogels from linear polyacrylamide crosslinked with glutaraldehyde

AU - Dmitriev, Ivan

AU - Kuryndin, Ivan

AU - Bobrova, Natalya

AU - Smirnov, Michael

N1 - Publisher Copyright: © 2015.

PY - 2015/9/1

Y1 - 2015/9/1

N2 - Polyacrylamide hydrogels have been prepared by crosslinking reaction between linear polyacrylamide (PAAm) and glutaraldehyde (GA) in acidic medium. The equilibrium swelling degree, modulus of elasticity and structure parameters of the network have been investigated as functions of the initial polymer concentration and the crosslinker content. Stability of GA crosslinks between PAAm chains has been demonstrated under the acid and basic conditions. It has been suggested that the crosslinking reaction can be presented as two stage process, which distinguishes different accessibility of aldehyde and amide groups for cross-linking agent in conditions of macromolecule distancing. The method provides formation of PAAm hydrogels with the values of the swelling degree and mechanical characteristics, which are close to the hydrogels prepared by traditional method of free radical crosslinking copolymerization.

AB - Polyacrylamide hydrogels have been prepared by crosslinking reaction between linear polyacrylamide (PAAm) and glutaraldehyde (GA) in acidic medium. The equilibrium swelling degree, modulus of elasticity and structure parameters of the network have been investigated as functions of the initial polymer concentration and the crosslinker content. Stability of GA crosslinks between PAAm chains has been demonstrated under the acid and basic conditions. It has been suggested that the crosslinking reaction can be presented as two stage process, which distinguishes different accessibility of aldehyde and amide groups for cross-linking agent in conditions of macromolecule distancing. The method provides formation of PAAm hydrogels with the values of the swelling degree and mechanical characteristics, which are close to the hydrogels prepared by traditional method of free radical crosslinking copolymerization.

UR - http://www.scopus.com/inward/record.url?scp=84933574742&partnerID=8YFLogxK

U2 - 10.1016/j.mtcomm.2015.06.005

DO - 10.1016/j.mtcomm.2015.06.005

M3 - Article

AN - SCOPUS:84933574742

VL - 4

SP - 93

EP - 100

JO - Materials Today Communications

JF - Materials Today Communications

SN - 2352-4928

ER -

ID: 100697733