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Surface chemistry of group IIA and IIIB fluorides in air by diffuse reflectance spectroscopy. / Tolstoi, V. P.; Zhuchkov, B. S.; Murin, I. V.

в: Inorganic Materials, Том 36, № 1, 01.01.2000, стр. 86-87.

Результаты исследований: Научные публикации в периодических изданияхстатьяРецензирование

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Tolstoi, V. P. ; Zhuchkov, B. S. ; Murin, I. V. / Surface chemistry of group IIA and IIIB fluorides in air by diffuse reflectance spectroscopy. в: Inorganic Materials. 2000 ; Том 36, № 1. стр. 86-87.

BibTeX

@article{79dd774481b04cd9828c65a75cb4829a,
title = "Surface chemistry of group IIA and IIIB fluorides in air by diffuse reflectance spectroscopy",
abstract = "The compounds forming on the surface of MgF2, SrF2, BaF2, ScF3,YF3, and LaF3 during storage in air were identified by Fourier-transform IR diffuse reflectance spectroscopy. The adlayer on the surface of MgF2 was found to contain magnesium hydroxide; on the surface of BaF2, YF3, and LaF3, basic carbonates were present. The mechanisms of the possible surface reactions are discussed, and a procedure is proposed which allows one to replace hydroxide-carbonate surface groups by fluoride groups and to enhance the stability of the fluoride surface to atmospheric attack.",
author = "Tolstoi, {V. P.} and Zhuchkov, {B. S.} and Murin, {I. V.}",
year = "2000",
month = jan,
day = "1",
doi = "10.1007/BF02758388",
language = "English",
volume = "36",
pages = "86--87",
journal = "Inorganic Materials",
issn = "0020-1685",
publisher = "МАИК {"}Наука/Интерпериодика{"}",
number = "1",

}

RIS

TY - JOUR

T1 - Surface chemistry of group IIA and IIIB fluorides in air by diffuse reflectance spectroscopy

AU - Tolstoi, V. P.

AU - Zhuchkov, B. S.

AU - Murin, I. V.

PY - 2000/1/1

Y1 - 2000/1/1

N2 - The compounds forming on the surface of MgF2, SrF2, BaF2, ScF3,YF3, and LaF3 during storage in air were identified by Fourier-transform IR diffuse reflectance spectroscopy. The adlayer on the surface of MgF2 was found to contain magnesium hydroxide; on the surface of BaF2, YF3, and LaF3, basic carbonates were present. The mechanisms of the possible surface reactions are discussed, and a procedure is proposed which allows one to replace hydroxide-carbonate surface groups by fluoride groups and to enhance the stability of the fluoride surface to atmospheric attack.

AB - The compounds forming on the surface of MgF2, SrF2, BaF2, ScF3,YF3, and LaF3 during storage in air were identified by Fourier-transform IR diffuse reflectance spectroscopy. The adlayer on the surface of MgF2 was found to contain magnesium hydroxide; on the surface of BaF2, YF3, and LaF3, basic carbonates were present. The mechanisms of the possible surface reactions are discussed, and a procedure is proposed which allows one to replace hydroxide-carbonate surface groups by fluoride groups and to enhance the stability of the fluoride surface to atmospheric attack.

UR - http://www.scopus.com/inward/record.url?scp=0033788418&partnerID=8YFLogxK

U2 - 10.1007/BF02758388

DO - 10.1007/BF02758388

M3 - Article

AN - SCOPUS:0033788418

VL - 36

SP - 86

EP - 87

JO - Inorganic Materials

JF - Inorganic Materials

SN - 0020-1685

IS - 1

ER -

ID: 42175151